Abstract

This review—which is based on the authors’ original studies—is devoted to application of aqueous solutions of Mo–V–P heteropoly acids (HPA-x, where x is the number of vanadium atoms) as bifunctional (acidic and oxidative) catalysts. The focus is on the development of one-pot processes in which the acid-catalyzed reaction of diene synthesis is combined with the oxidation of the produced adducts. Prospects for the design of a number of industrial processes for the production of substituted 1,4-naphtho- and 9,10-anthraquinones in the presence of solutions of modified non-Keggin HPA-x are shown.

中文翻译：

---

Mo–V–P杂多酸溶液存在下的二烯合成和一锅法

摘要

这篇综述基于作者的原始研究，致力于将Mo–V–P杂多酸（HPA- x，其中x是钒原子数）的水溶液用作双功能（酸性和氧化性）催化剂。重点是一锅法的发展，其中酸催化的二烯合成反应与生成的加合物的氧化结合在一起。显示了在修饰的非Keggin HPA- x溶液存在下生产取代的1,4-萘-和9,10-蒽醌的许多工业方法的设计前景。