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Silver doping in lanthanum manganite materials: structural and electrical properties
Journal of Thermal Analysis and Calorimetry ( IF 4.4 ) Pub Date : 2020-08-03 , DOI: 10.1007/s10973-020-10095-1
Paula Sfirloaga , Gabriela Vlase , Titus Vlase , Iosif Malaescu , Catalin Nicolae Marin , Paulina Vlazan

Ag-doped LaMnO3 nanoparticles have been synthesized through sol–gel process using citric acid as a chelating agent. Silver effect on physicochemical properties was studied. The physicochemical properties and electrical performance of the obtained materials were also investigated, using thermogravimetric analysis (TGA) and X-ray diffraction (XRD) techniques. Thermogravimetric analysis shows that for the studied materials a decomposition stage between 3.7% and 4.1% can be observed, and mass increases from the LMN-Ag1 to the LMN-Ag3 sample. Also, in all those three situations an endothermic process with a maximum around 600 °C is observed. The diffractograms of the perovskite materials showed single-phase crystalline with high purity and rhombohedral structure with R-3c space group. The electrical measurements show that the conductivity spectrum is formed by both the static component σDC corresponding to the low frequencies and the component σAC corresponding to high frequencies. The values of σDC of samples are significantly influenced by the silver ions concentration.



中文翻译:

镧锰材料中的银掺杂:结构和电性能

掺银LaMnO 3纳米颗粒通过柠檬酸作为螯合剂通过溶胶-凝胶法合成。研究了银对理化性质的影响。还使用热重分析(TGA)和X射线衍射(XRD)技术研究了所得材料的理化性质和电性能。热重分析表明,对于所研究的材料,可以观察到3.7%至4.1%的分解阶段,并且从LMN-Ag1到LMN-Ag3样品的质量增加。同样,在所有这三种情况下,都观察到最高约600°C的吸热过程。钙钛矿材料的衍射图显示出具有高纯度的单相晶体和具有R-3c空间基团的菱形结构。σ DC对应于低频率成分和σ AC对应于高频率。的值σ DC样品的由银离子浓度显著影响。

更新日期:2020-08-03
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