当前位置: X-MOL 学术J. Iran. Chem. Soc. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Studies of the photocatalytic and electrochemical performance of the Fe 2 O 3 /TiO 2 heteronanostructure
Journal of the Iranian Chemical Society ( IF 2.4 ) Pub Date : 2020-08-03 , DOI: 10.1007/s13738-020-01993-0
Abdelhak Othmani , Salah Kouass , Thamer Khalfi , Sabrine Bourchada , Fathi Touati , Hassouna Dhaouadi

The α-Fe2O3/TiO2 nanostructure material, synthesized on FTO (fluorine-doped tin oxide) substrate using the hydrothermal method at 180 °C for 5 h, exhibits an enhanced performance in the photocatalytic degradation of an organic dye. The optical band gap was found to decrease compared to the TiO2 one. The photocatalytic performances of the as-prepared heterojunction were evaluated with the degradation of methylene blue (MB) in an aqueous medium. The results revealed that the photocatalytic activity of the Fe2O3/TiO2/FTO was much higher than that of the pure TiO2. In addition, the photocurrent of the Fe2O3/TiO2/FTO heterojunction was remarkably higher than that of the bare TiO2 electrode. The obtained results indicate that the heterojunction formed between Fe2O3 and TiO2significantly improved the separation efficiency of the photo-generated electron–hole pairs. The electrochemical properties of the as-synthesized nanocomposite materials (α-Fe2O3/TiO2) were also evaluated with cyclic voltammetry for 1000 cycles. This nanocomposite exhibited an enhanced specific discharge capacity compared to the Fe2O3 nanomaterial. The as-produced material proved to have an impressive performance as a high-capacity anode for Na+-ion batteries.



中文翻译:

Fe 2 O 3 / TiO 2杂纳米结构的光催化和电化学性能研究

所述的α-Fe 2 ö 3 /二氧化钛2纳米结构材料,采用水热法,在180上FTO(氟掺杂的氧化锡)衬底合成℃下保持5小时,表现出的有机染料的光催化降解的增强的性能。发现与TiO 2相比,光学带隙减小。制备的异质结的光催化性能通过在水介质中降解亚甲基蓝(MB)进行评估。结果表明,Fe 2 O 3 / TiO 2 / FTO的光催化活性远高于纯TiO 2。另外,Fe 2 O的光电流3 / TiO 2 / FTO异质结明显高于裸露的TiO 2电极。所得结果表明,Fe 2 O 3和TiO 2之间形成的异质结显着提高了光生电子-空穴对的分离效率。所合成的纳米复合物材料的电化学性能(的α-Fe 2 ö 3 /二氧化钛2)也与循环伏安法评价1000个循环。与Fe 2 O 3相比,该纳米复合材料表现出增强的比放电容量纳米材料。事实证明,这种制成的材料作为Na +离子电池的高容量阳极具有令人印象深刻的性能。

更新日期:2020-08-03
down
wechat
bug