The C(sp3)–H bond is found widely in organic molecules. Recently, the functionalization of C(sp3)–H bonds has developed into a powerful tool for augmenting highly functionalized frameworks in organic synthesis. Based on the results obtained in our group, the present account mainly summarizes recent progress on the functionalization of C(sp3)–H bonds of aliphatic alcohols, ketones, alkyl nitriles, and ethers with styrene or cinnamic acid using tert-butyl hydroperoxide (TBHP) as a radical initiator. 1 Introduction 2 Oxidative Coupling of Styrenes with C(sp3)–H Bonds 3 Decarboxylative Cross-Couplings of α,β-Unsaturated Carboxylic Acids with C(sp3)–H Bonds 4 Conclusions

中文翻译：

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使用叔丁基过氧化氢作为自由基引发剂的醇、酮、腈、醚和酰胺的 C(sp3)-H 键官能化

C(sp3)-H 键广泛存在于有机分子中。最近，C(sp3)-H 键的功能化已发展成为增强有机合成中高度功能化框架的有力工具。基于我们组获得的结果，本报告主要总结了使用叔丁基过氧化氢（TBHP）与苯乙烯或肉桂酸对脂肪醇、酮、烷基腈和醚的 C(sp3)-H 键进行功能化的最新进展) 作为自由基引发剂。1 引言 2 苯乙烯与 C(sp3)-H 键的氧化偶联 3 α,β-不饱和羧酸与 C(sp3)-H 键的脱羧交叉偶联 4 结论