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Extraction of lipids from post-hydrolysis spent coffee grounds for biodiesel production with hexane as solvent: Kinetic and equilibrium data
Biomass & Bioenergy ( IF 6 ) Pub Date : 2020-08-01 , DOI: 10.1016/j.biombioe.2020.105704
Alchris Woo Go , Thi Yen Nhu Pham , Yi-Hsu Ju , Ramelito C. Agapay , Artik Elisa Angkawijaya , Kristelle L. Quijote

Spent coffee grounds (SCG), an agro-industrial residue produced after brewing of coffee beans contains appreciable amounts of lipids (~16 wt%). One way of valorizing SCG is to subject it to dilute acid hydrolysis for the production of sugar-rich hydrolysate and lipid-dense post-hydrolysis residue. The post-hydrolysis spent coffee grounds (PHSCG) contains substantial amounts of lipids (~26 wt%), making it necessary to gather lipid extraction kinetics and equilibrium data for process and equipment design. The effects of solvent-to-solid ratio (4–20 mL g−1) and temperature (30–60 °C) on the kinetics and equilibrium of lipid extraction from PHSCG using hexane as solvent was investigated. To appropriately describe the lipid extraction system, various kinetic models were fitted, with multi-step models best representing the extraction process (R2 ≥ 0.99). Regardless of extraction temperature and SSR, washing step equilibrium is reached at a very short extraction time (<10 min) and over 90% of the lipids can be extracted in at least 1 h. Extraction of lipids from PHSCG required less amount of solvent to extract and recover the same amount of lipids present in SCG saving up to 40% of the solvent required for lipid extraction from SCG.



中文翻译:

从水解后的废咖啡渣中提取脂质,以己烷为溶剂生产生物柴油:动力学和平衡数据

用过的咖啡渣(SCG)是咖啡豆冲泡后产生的一种农业工业残留物,含有大量的脂质(〜16 wt%)。使SCG增值的一种方法是对其进行稀酸水解,以生产富含糖的水解产物和脂质密集的水解后残留物。水解后的废咖啡渣(PHSCG)包含大量脂质(〜26 wt%),因此有必要收集脂质提取动力学和平衡数据以进行工艺和设备设计。溶剂与固体之比(4–20 mL g -1)和温度(30–60°C)对以己烷为溶剂从PHSCG提取脂质的动力学和平衡进行了研究。为了适当地描述了脂质提取系统,各种动力学模型拟合,与多步模型最好代表提取处理(R 2  ≥0.99)。无论提取温度和SSR如何,在很短的提取时间(<10分钟)内都能达到洗涤步骤平衡,并且至少1小时内可以提取90%以上的脂质。从PHSCG提取脂质需要较少量的溶剂才能提取和回收SCG中存在的相同量的脂质,从而节省了多达40%的从SCG提取脂质所需的溶剂。

更新日期:2020-08-01
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