Abstract

Considering the widespread interest in the chiroptical properties of materials, especially circularly polarized luminescence (CPL), the functionalization of bipyrenol (BPy) was carried out aiming at future advanced chiral materials (ACMs) in which BPy shows a high quantum yield and clear CPL spectra. To create ACMs using BPy units that contain nucleophilic substituents, amine and thiol were selected as the functional group and attached to BPy by means of alkyl linkages. The obtained thiol and amine derivatives are stable under ambient conditions. To demonstrate the potential of these molecules, photoinduced electron-transfer systems were synthesized.

中文翻译：

---

Bipyrenol的功能化：高级手性分子的潜在前体。

摘要

考虑到人们对材料的手性特别是圆偏振发光（CPL）的广泛兴趣，联苯三酚（BPy）的功能化是针对未来的高级手性材料（ACM）进行的，其中BPy具有高量子产率和清晰的CPL光谱。为了使用含有亲核取代基的BPy单元创建ACM，选择胺和硫醇作为官能团，并通过烷基键连接到BPy。所获得的硫醇和胺衍生物在环境条件下是稳定的。为了证明这些分子的潜力，合成了光诱导电子转移系统。