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Hierarchical Porous Graphene-Iron Carbide Hybrid Derived From Functionalized Graphene-Based Metal-Organic Gel as Efficient Electrochemical Dopamine Sensor.
Frontiers in Chemistry ( IF 5.5 ) Pub Date : 2020-05-27 , DOI: 10.3389/fchem.2020.00544
Eleni C Vermisoglou 1 , Petr Jakubec 1 , Ondřej Malina 1 , Vojtěch Kupka 1 , Andreas Schneemann 2, 3 , Roland A Fischer 2 , Radek Zbořil 1 , Kolleboyina Jayaramulu 1, 2, 4 , Michal Otyepka 1
Affiliation  

A metal–organic gel (MOG) similar in constitution to MIL-100 (Fe) but containing a lower connectivity ligand (5-aminoisophthalate) was integrated with an isophthalate functionalized graphene (IG). The IG acted as a structure-directing templating agent, which also induced conductivity of the material. The MOG@IG was pyrolyzed at 600°C to obtain MGH-600, a hybrid of Fe/Fe3C/FeOx enveloped by graphene. MGH-600 shows a hierarchical pore structure, with micropores of 1.1 nm and a mesopore distribution between 2 and 6 nm, and Brunauer–Emmett–Teller surface area amounts to 216 m2/g. Furthermore, the MGH-600 composite displays magnetic properties, with bulk saturation magnetization value of 130 emu/g at room temperature. The material coated on glassy carbon electrode can distinguish between molecules with the same oxidation potential, such as dopamine in presence of ascorbic acid and revealed a satisfactory limit of detection and limit of quantification (4.39 × 10−7 and 1.33 × 10−6 M, respectively) for the neurotransmitter dopamine.



中文翻译:

源自功能化石墨烯基金属有机凝胶的分层多孔石墨烯-碳化铁杂化物作为高效电化学多巴胺传感器。

金属有机凝胶(MOG)与 MIL-100(Fe)结构相似,但含有较低连接性配体(5-氨基间苯二甲酸酯),与间苯二甲酸酯官能化石墨烯(IG)集成。IG 充当结构导向模板剂,也诱导材料的导电性。MOG@IG在600℃下热解得到MGH-600,一种石墨烯包覆的Fe/Fe 3 C/FeO x杂化物。MGH-600显示出分级孔结构,微孔为1.1 nm,中孔分布在2至6 nm之间,Brunauer-Emmett-Teller表面积达216 m 2 / g。此外,MGH-600复合材料表现出磁性能,室温下体饱和磁化强度值为130 emu/g。涂覆在玻碳电极上的材料可以区分具有相同氧化电位的分子,例如抗坏血酸存在下的多巴胺,并显示出令人满意的检测限和定量限(4.39 × 10 -7 和 1.33 × 10 -6 M,分别)为神经递质多巴胺。

更新日期:2020-07-30
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