Amorphization scenarios in multiparticulate grinding media composed of As₄S₄/ZnS/Fe₃O₄ nanocomposites driven by high-energy ball mechanical milling are identified employing the X-ray powder diffraction analysis on intermediate-range ordering in the generated amorphous phase. This amorphous phase is supposed to be nucleated heterogeneously from grain boundaries of β-As₄S₄ crystallites followed by penetration deeply into grain interior, stabilizing the crystalline-amorphous core-shell structure of the fine-grained nanoparticles. Coexistence of nanocrystalline nc-β-As₄S₄ and amorphous arsenic monosulphide a-AsS phases is crucial feature of these nanocomposites, the amorphous substance being generated continuously due to re-amorphization of disordered phase initially existed in arsenic sulphide prepared by synthesis from elements and direct milling-driven vitrification of nc-β-As₄S₄. In monoparticulate β-As₄S₄-based and biparticulate As₄S₄/Fe₃O₄ nanocomposites, the amorphizing configurations are composed of single- and triple-broken chain-like network clusters. Under stronger conditions realized in the grinding medium composed by hard nanoparticles biased by their sizes in respect to 20:1 rule, as in triparticulate 1⋅As₄S₄-4⋅ZnS-1⋅Fe₃O₄ nanocomposite, the amorphization scenario differs being activated by double-breaking of intramolecular covalent bonds within As₄S₄ cage-like molecules. This effect is identified as nanocrystalline nc-ZnS-assisted milling-driven arsenic monosulphide amorphization in triparticulate 1⋅β-As₄S₄-4⋅ZnS-1⋅Fe₃O₄ nanocomposite solution.

利用X射线粉末衍射分析法对生成的非晶相中的中间有序化，确定了由高能球机械研磨驱动的由As ₄ S ₄ / ZnS / Fe ₃ O ₄纳米复合材料组成的多颗粒研磨介质中的非晶化情况。该非晶相被认为是从β- As ₄ S ₄晶粒的晶界异质成核，然后深深渗透到晶粒内部，从而稳定了细颗粒纳米粒子的晶体-非晶核-壳结构。纳米晶nc- β- As ₄ S _4的共存这些纳米复合材料的关键特征是无定形单硫化砷a-AsS相，无定形物质是由于无序相的重新非晶化而不断产生的，该无序相最初存在于通过元素合成和直接研磨驱动nc- β的玻璃化而制备的硫化砷中。作为₄ S ₄。在monoparticulate β -As ₄小号₄基和biparticulate作为₄小号₄ / Fe的₃ ö ₄纳米复合材料，非晶态结构由单断裂和三断裂链状网络簇组成。下通过可以通过在相对于尺寸偏置到20硬质纳米颗粒构成的研磨介质来实现更强的条件：1个规则，如在triparticulate1⋅As ₄小号₄ -4⋅ZnS-1⋅Fe ₃ ö ₄的纳米复合材料，非晶化方案的不同之被As ₄ S ₄笼状分子内的分子内共价键双断裂激活。这种效应被识别为纳米晶NC-的ZnS辅助碾磨驱动砷单硫化物在非晶triparticulate1⋅β-作为₄小号₄ -4⋅ZnS-1⋅Fe ₃ ö₄纳米复合溶液。