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The Effect of the Phase Structure of Silane-Modified Ethylene Copolymers on Their Surface Energy and Adhesion Properties
Polymer Science, Series D Pub Date : 2020-07-01 , DOI: 10.1134/s1995421220030156
S. N. Rusanova , S. Yu. Sof’ina , N. E. Temnikova , V. K. Gerasimov , A. E. Chalykh , I. A. Starostina , Zh. V. Mezhevich , O. V. Stoyanov

Systems consisting of ethylene–vinyl acetate copolymers and (aminoalkoxy)silanes are studied. The diffusion and mutual solubility of their components are investigated, and phase diagrams covering a broad range of composition and temperatures are constructed. We find that the near-surface layers of the modified copolymers are enriched with the organosilicon component. The effects that the phase structure of considered adhesives has on the energetic properties and adhesion strength for different types of substrates are identified.

中文翻译:

硅烷改性乙烯共聚物的相结构对其表面能和粘附性能的影响

研究了由乙烯-乙酸乙烯酯共聚物和(氨基烷氧基)硅烷组成的系统。研究了它们组分的扩散和互溶性,并构建了涵盖广泛组成和温度范围的相图。我们发现改性共聚物的近表面层富含有机硅成分。确定了所考虑粘合剂的相结构对不同类型基材的能量特性和粘合强度的影响。
更新日期:2020-07-01
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