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Experimentally Designed Natural Light Induced Photocatalytic Performance of Nanostructured Eu 2 Ce 2 O 7 Synthesized by a Facile Solid State Method in Removal of Environmental Pollutant Malachite Green (MG)
Proceedings of the National Academy of Sciences, India Section A: Physical Sciences ( IF 0.9 ) Pub Date : 2020-07-29 , DOI: 10.1007/s40010-020-00697-7
Mina Dolatalizadeh , Mahdi Behzad , Shahin Khademinia , Ali Arab

Nanopowders of Eu2Ce2O7 were synthesized via solid-state reactions between Eu2O3 and (NH4)2Ce(NO3)6 raw materials at stoichiometric 1:1 Eu/Ce molar ratio at 800 °C (S1), 900 °C (S2), 1000 °C (S3) for 8 h and 1000 °C for 10 h (S4). The synthesized materials were characterized by powder X-ray diffraction (PXRD) technique. Structural analyses were performed by FullProf program employing profile matching with constant scale factors. The results showed that the patterns had a main Eu2Ce2O7 structure with a space group of \({\text{Fm}}\overline{3}{\text{m}}\). FESEM images showed that the synthesized Eu2Ce2O7 particles had mono-shaped sphere morphologies. Ultraviolet–visible spectra showed that the nanostructured Eu2Ce2O7 powders possessed strong light absorption properties in the ultraviolet–visible light region. The direct optical band gap energies were 3.08 eV (S1), 3.05 eV (S2), 2.91 eV (S3) and 2.74 eV (S4). Photocatalytic performance of the synthesized nanomaterials was investigated for the degradation of pollutant Malachite Green (4-{[4-(dimethylamino)phenyl](phenyl)methylidene}-N'N-dimethylcyclohexa-25-dien-1-iminium chloride) (MG) in aqueous solution under solar light condition. The optimum conditions were modeled and obtained by design expert software for S1 which were 0.4 ml H2O2, 20 mg catalyst and 60 min for the removal of 60 ml of 50 ppm MG solutions. The degradation yield in these conditions was 93% for (S1).



中文翻译:

实验设计的自然光诱导的简易固态方法合成的Eu 2 Ce 2 O 7纳米结构的光催化性能去除环境污染的孔雀石绿(MG)

通过Eu 2 O 3与(NH 42 Ce(NO 36原料在800°C(S的化学计量比为1:1 )之间的固相反应合成了Eu 2 Ce 2 O 7纳米粉体。1),900°C(S 2),1000°C(S 3)8小时和1000°C 10小时(S 4)。通过粉末X射线衍射(PXRD)技术对合成的材料进行了表征。结构分析由FullProf进行程序使用轮廓匹配且比例因子恒定的程序。结果表明,这些图案具有主要的Eu 2 Ce 2 O 7结构,其空间群为\({\ text {Fm}} \ overline {3} {\ text {m}} \\}。FESEM图像显示,合成的Eu 2 Ce 2 O 7颗粒具有单形球形形态。紫外可见光谱表明,纳米结构的Eu 2 Ce 2 O 7粉末在紫外可见光区域具有很强的吸光性能。直接光学带隙能量为3.08 eV(S 1),3.05 eV(S 2),2.91 eV(S3)和2.74 eV(S 4)。研究了合成的纳米材料的光催化性能,用于降解孔雀石绿(4-{[4-(二甲基氨基)苯基](苯基)亚甲基} -N'N-二甲基环己-25-二烯-1-亚胺氯化铵)(MG )在阳光下的水溶液中。的最佳条件进行了建模,并通过设计专家软件,用于S取得1,其分别为0.4毫升水2 ö 2,20毫克催化剂和60分钟以除去60毫升50ppm的MG的解决方案。在这些条件下,(S 1)的降解率为93%。

更新日期:2020-07-30
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