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Greatly enhanced permittivity in BaTiO3-epoxy dielectric composites with improved connectivity of ceramic phase
Journal of Materiomics ( IF 9.4 ) Pub Date : 2020-07-29 , DOI: 10.1016/j.jmat.2020.07.007
Meng Cao , Lei Li , Wen Bin Hong , Shu Ya Wu , Xiang Ming Chen

BaTiO3-epoxy dielectric composites were prepared by curing the liquid epoxy monomer that infiltrated into the partially-sintered BaTiO3 porous ceramics. The BaTiO3 volume fraction of the composites maintained around 58.6% with increasing the sintering temperature from 600 °C to 1000 °C, while the significant microstructure evolution, improved connectivity of BaTiO3 phase and dramatical increase in permittivity from 102 to 697 were observed. The permittivity and BaTiO3 volume fraction further increased to 2328 and 83.5% for the sintering temperature of 1250 °C. The present composites had the permittivity 1–2 orders of magnitude higher than the 0–3 type ones, and the extraordinary results were mainly attributed to the improved connectivity of BaTiO3 phase that benefited from partial sintering. The connectivity also had a significant effect on the temperature dependence of permittivity, and good combination of temperature-stable high permittivity, low dielectric loss and relatively low ceramic fraction could be obtained by regulating the connectivity of BaTiO3 ceramic phase.



中文翻译:

大大提高了BaTiO 3-环氧介电复合材料的介电常数,改善了陶瓷相的连通性

通过固化渗透到部分烧结的BaTiO 3多孔陶瓷中的液态环氧单体,制备了BaTiO 3-环氧介电复合材料。随着烧结温度从600°C增加到1000°C,复合材料的BaTiO 3体积分数保持在58.6%左右,同时观察到显着的微观结构演变,BaTiO 3相的改善的连通性和介电常数从102到697的急剧增加。介电常数和BaTiO 3对于1250℃的烧结温度,体积分数进一步增加至2328和83.5%。目前的复合材料的介电常数比0-3型的介电常数高1-2个数量级,非凡的结果主要归因于部分烧结使BaTiO 3相的连通性得到了改善。连通性对介电常数的温度依赖性也具有显着影响,并且通过调节BaTiO 3陶瓷相的连通性,可以获得温度稳定的高介电常数,低介电损耗和相对较低的陶瓷分数的良好组合。

更新日期:2020-10-05
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