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Surface-tunable, electrically conductive and inexpensive graphene platelets and their hydrophilic polymer nanocomposites
Polymer ( IF 4.6 ) Pub Date : 2020-07-29 , DOI: 10.1016/j.polymer.2020.122851
Ruoyu Wang , Mathias Aakyiir , Aidong Qiu , Jeong-A. Oh , Philip Adu , Qingshi Meng , Jun Ma

A cost-effective method is essential for the applications of graphene platelets (GnPs) in polymer processing industry. Herein, a simple microwave expansion method was introduced to prepare graphene platelets (GnPs) of 11.7 ± 4.3 nm in thickness. By controlling the concentration of nitric acid, the surface of GnPs was tuned to be hydrophilic without causing severe damage to their structural integrity; the modified GnPs had thickness of 4.6 ± 2.1 nm, Raman ID/IG ratio of 0.09 and electrical conductivity of 570 S cm−1. The platelets' high crystallinity before and after the surface modification was proved by TEM and SAED analysis. A percolation threshold of electrical conductivity was found at 0.89 vol% for poly (vinyl alcohol)/modified GnP nanocomposites. The platelets at 0.5 vol% improved tensile strength by 91.1% and Young's modulus by 66.7% due to relatively uniform dispersion and strong interfacial interactions with the matrix.



中文翻译:

表面可调,导电且廉价的石墨烯薄片及其亲水性聚合物纳米复合材料

对于石墨烯血小板(GnP)在聚合物加工行业中的应用而言,一种具有成本效益的方法至关重要。在此,介绍了一种简单的微波膨胀方法来制备厚度为11.7±4.3 nm的石墨烯血小板(GnPs)。通过控制硝酸的浓度,可以将GnPs的表面调整为亲水性,而不会对其结构完整性造成严重损害。修饰的GnPs的厚度为4.6±2.1 nm,拉曼I D / I G比为0.09,电导率为570 S cm -1。通过TEM和SAED分析证明了表面改性前后血小板的高结晶度。对于聚乙烯醇/改性的GnP纳米复合材料,发现电导率的渗透阈值为0.89vol%。由于相对均匀的分散和与基质的强界面相互作用,0.5%(体积)的血小板使抗张强度提高了91.1%,杨氏模量提高了66.7%。

更新日期:2020-07-29
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