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Experimental investigation of phase equilibria in the Co–Fe–La system at 600 and 500 °C
Calphad ( IF 2.4 ) Pub Date : 2020-07-29 , DOI: 10.1016/j.calphad.2020.101794
I. Fartushna , M. Mardani , A. Khvan , V. Cheverikin , A. Kondratiev

Phase equilibria in the Co–Fe–La ternary system have been studied using X-ray diffraction (XRD), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA). Isothermal sections at 600 (in the whole concentration region) and 500 °C (in the La-rich region) for this system have been constructed. It was shown that the ternary compound La2(Co,Fe)17 (τ) (Th2Zn17-type structure) is stable at 600 °C and has homogeneity range from 67 to 72 at.% Co. It co-exists with the majority of solid phases (αFe,Co), LaCo13, LaCo5, La2Co7 and La2Co3 at 600 °C. The LaCo13 phase has the widest homogeneity region and dissolves up to 32.5 at.% Fe at 600 °C. The character of phase equilibria at 500 °C in the studied region is similar to those at solidus temperature. The character of phase equilibria at 600 °C is different from those at the solidus temperature. The main difference involves the fact that the equilibrium τ + LaCo5 which is present in the Co–Fe–La system at solidus temperature, is absent at 600 °C. Instead, the alternative equilibrium (αFe,Co) + La2Co7 is present at 600 °C.



中文翻译:

Co-Fe-La系统在600和500°C下相平衡的实验研究

使用X射线衍射(XRD),扫描电子显微镜(SEM)和电子探针显微分析(EPMA)研究了Co-Fe-La三元体系中的相平衡。已经为该系统构建了600(在整个浓度区域)和500°C(在La富集区域)的等温截面。结果表明,三元化合物La 2(Co,Fe)17(τ)(Th 2 Zn 17型结构)在600°C下稳定,并且Co的均质度为67至72 at。%。在600°C下具有大多数固相(αFe,Co),LaCo 13,LaCo 5,La 2 Co 7和La 2 Co 3。LaCo 13相具有最宽的均匀性区域,并且在600°C时可溶解高达32.5 at。%的Fe。研究区在500°C时的相平衡特性与固相线温度相类似。600°C下的相平衡特性与固相线温度下的相平衡特性不同。主要区别在于以下事实:在固相线温度下,Co–Fe–La系统中不存在平衡τ+ LaCo 5,但温度为600°C。相反,替代平衡(αFe,Co)+ La 2 Co 7在600°C存在。

更新日期:2020-07-29
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