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Mechanism of the Conversion of γ-Аl 2 О 3 Nanopowder into Boehmite under Hydrothermal Conditions
Inorganic Materials ( IF 0.8 ) Pub Date : 2020-07-28 , DOI: 10.1134/s0020168520070092
I. V. Kozerozhets , G. P. Panasyuk , E. A. Semenov , I. L. Voroshilov , L. A. Azarova , V. N. Belan

Abstract

We have developed a method for the preparation of boehmite (AlOOH) nanopowder with tailored properties (particle size from 10 to 40 nm, thermal conductivity below 0.02 W/(m K), specific surface area on the order of 65 m2/g, and loose bulk density in the range 0.02–0.04 g/cm3) by hydrothermal treatment of γ‑Аl2О3 nanopowder in a 1.5% HCl solution at 200°C. The steps of the process have been identified and it has been shown to be a solid-state (topochemical) transformation.


中文翻译:

水热条件下γ-Аl2О3纳米粉体转化为勃姆石的机理

摘要

我们已经开发出一种制备具有定制特性的勃姆石(AlOOH)纳米粉的方法(粒径为10至40 nm,导热系数低于0.02 W /(m K),比表面积约为65 m 2 / g,并在范围0.02-0.04克/厘米松堆积密度3由γ-Аl的水热处理)2 О 3在200℃的1.5%HCl溶液纳米粉末。该过程的步骤已经确定,并且已经证明是固态(拓扑化学)转化。
更新日期:2020-07-28
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