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Experimental Vapor Pressures of Hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (RDX) and Hexahydro‐1,3,5‐trinitroso‐1,3,5‐triazine (TNX)
Propellants, Explosives, Pyrotechnics ( IF 1.8 ) Pub Date : 2020-07-28 , DOI: 10.1002/prep.202000098
Greta Bikelytė 1 , Martin A. C. Härtel 1 , Thomas M. Klapötke 1
Affiliation  

In this work experimental vapor pressures of hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (RDX) and hexahydro‐1,3,5‐trinitroso‐1,3,5‐triazine (TNX) were measured with transpiration method. Corresponding enthalpies of sublimation were determined to be (130.9±2.1) kJ mol−1 and (108.1±1.6) kJ mol−1, respectively. Along with the experimental data fitting equations are reported and p‐T data extrapolated to 298.15 K to be 0.71 μPa for RDX and 823 μPa for TNX.

中文翻译:

六氢-1,3,5-三硝基-1,3,5-三嗪(RDX)和六氢-1,3,5-三亚硝基-1,3,5-三嗪(TNX)的实验蒸气压

在这项工作中,测量了六氢-1,3,5-三硝基-1,3,5-三嗪(RDX)和六氢-1,3,5-三亚硝基-1,3,5-三嗪(TNX)的实验蒸气压用蒸腾法。相应的升华焓确定为(130.9±2.1)kJ mol -1和(108.1±1.6)kJ mol -1。报告了实验数据拟合方程,并将p‐T数据外推至298.15 K,对于RDX为0.71μPa,对于TNX为823μPa。
更新日期:2020-10-05
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