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Zinc ion-imprinted polymer based on silica particles modified carbon paste electrodes for highly selective electrochemical determination of zinc ions
Polymer-Plastics Technology and Materials ( IF 2.7 ) Pub Date : 2020-06-18 , DOI: 10.1080/25740881.2020.1765381
Nilesh A. Khairnar 1 , Harishchandra D. Jirimali 1, 2 , Kailas P. Patil 3 , Vikas V. Gite 1
Affiliation  

In this study, Zn(II) ion-imprinted polymer was prepared on the surface of vinyl silica particles and applied for detection of Zn(II) ions using differential pulse voltametry. The ion- imprinted polymer particles were prepared by free radical polymerization. The prepared particles were characterized by different morphological and elemental techniques. The ion-imprinted particles were used to fabricate the carbon paste electrode as a zinc ions sensor. The modified zinc sensor showed linear response in the concentration range 6.12 × 10−9 to 4.59 × 10−8 mol L−1. The limit of detection and limit of quantification of the electrode were 1.351 × 10−8 and 4.094 × 10−8 mol L−1, respectively.



中文翻译:

基于二氧化硅颗粒修饰的碳糊电极的锌离子印迹聚合物,用于高选择性电化学测定锌离子

在这项研究中,在乙烯基二氧化硅颗粒的表面上制备了Zn(II)离子印迹聚合物,并使用差分脉冲伏安法将其用于检测Zn(II)离子。通过自由基聚合制备离子印迹聚合物颗粒。通过不同的形态学和元素技术表征了制备的颗粒。离子印迹颗粒用于制造碳糊电极,作为锌离子传感器。改进的锌传感器在6.12×10 -9至4.59×10 -8  mol L -1的浓度范围内显示线性响应。电极的检测极限和定量极限分别为1.351×10 -8和4.094×10 -8  mol L -1

更新日期:2020-07-24
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