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Performance improvement strategies of CuWO4 photocatalyst for hydrogen generation and pollutant degradation
Journal of Environmental Chemical Engineering ( IF 7.7 ) Pub Date : 2020-06-29 , DOI: 10.1016/j.jece.2020.104230
Pankaj Raizada , Sonali Sharma , Abhinandan Kumar , Pardeep Singh , Aftab Aslam Parwaz Khan , Abdullah M. Asiri

Recently, photocatalysis has attracted all-embracing attention as a sustainable and green approach owing to its promising applications in the deterioration of contaminants along with the transformation of solar energy into chemical energy. An efficient visible-light harnessing Copper tungstate photocatalyst has hooked excellent performance because of its peculiar features, including eco-friendliness, low cost, optimum band edge potentials, as well as stability under oxidative and acidic conditions. However, any review depicting the correlation between different morphologies, properties, and performance of CuWO4 is still absent. Therefore, this review highlighted the energy applications of CuWO4 photocatalyst, focusing on its morphological dimensions and strategies for photocatalytic performance enhancement. Various fabrication methods, such as hydrothermal, electrodeposition, spray-pyrolysis, co-precipitation, sonochemistry, and solid-state synthesis, are also discussed. Controllable synthesis of distinct morphological nanostructures with the effect of parameters like temperature, pH, solvent, reaction time, and concentration of precursors has been briefly summarized. Nano-structured CuWO4 was explored to show high photocatalytic activity than pristine CuWO4. Moreover, different revamp strategies, including doping of parent photocatalyst, loading of co-catalyst on photocatalyst surface, and heterojunction construction, are assumed for the efficient space charge isolation of photo charge carriers suppressing the rapid recombination of photo-generated electron-hole pairs for dynamic photocatalytic activity. The applications of CuWO4, including photocatalytic water reduction for H2 generation, photodegradation of dyes and antibiotics, and photoelectrochemical water splitting, have been highlighted. Finally, a brief, conclusive remark regarding present studies and unresolved challenges of nano-structured CuWO4 are put forth for future perspectives.



中文翻译:

CuWO 4光催化剂在制氢和降解污染物方面的性能改进策略

近年来,光催化作为一种​​可持续的绿色方法已引起了广泛的关注,这是由于光催化在将污染物转化为太阳能以及将其转化为化学能方面具有广阔的前景。高效的可见光治理钨酸铜光催化剂因其独特的功能(包括环保,低成本,最佳的带边电势以及在氧化和酸性条件下的稳定性)而获得了出色的性能。但是,仍然没有任何描述CuWO 4的不同形态,性质和性能之间的相关性的综述。因此,本综述着重介绍了CuWO 4的能源应用光催化剂,着重于其形态尺寸和提高光催化性能的策略。还讨论了各种制造方法,例如水热法,电沉积法,喷雾热解法,共沉淀法,声化学法和固态合成法。简要总结了受温度,pH,溶剂,反应时间和前体浓度等参数影响的独特形态纳米结构的可控合成。探索了纳米结构的CuWO 4表现出比原始CuWO 4高的光催化活性。此外,为提高光电荷载流子的有效空间电荷隔离率,抑制了光生电子-空穴对的快速重组,假定采用不同的改型策略,包括母体光催化剂的掺杂,光催化剂表面上助催化剂的负载以及异质结的构造。动态光催化活性。CuWO 4的应用已被强调,包括用于H 2生成的光催化减水,染料和抗生素的光降解以及光电化学水分解。最后,针对当前研究和纳米结构CuWO 4的未解决挑战提出了简短的结论性意见,以备将来使用。

更新日期:2020-07-24
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