Green and sustainable synthesis of zeolites has been continuously developed because of the requirement of environmental concerns. Among these efforts, it is very successful for organotemplate-free synthesis of aluminophosphate and silicoaluminophosphate molecular sieves and pure silica zeolites. In general, for the synthesis of aluminophosphate-based molecular sieves and many aluminosilicate zeolites, it is necessary to use organic templates, resulting in the formation of a huge amount of polluted wastes, which are environmentally unfriendly. In 2008, we show first example for organotemplate-free synthesis of aluminosilicate Beta, where the organic template of tetraethylammonium hydroxide in the conventional synthesis is completely avoided. However, it still has a challenge for organotemplate-free synthesis of other important aluminophosphate-based molecular sieves and pure silica zeolites. In this short review, it is briefly summarized recent advances in organotemplate-free synthesis of aluminophosphate and silicoaluminophosphate molecular sieves and pure silica zeolites, which are green and sustainable compared with those synthesized in the presence of organic templates.

由于对环境的关注，绿色和可持续的沸石合成一直在不断发展。在这些努力中，它非常成功地用于无有机模板的铝磷酸盐和硅铝磷酸盐分子筛以及纯二氧化硅沸石的合成。通常，为了合成基于铝磷酸盐的分子筛和许多铝硅酸盐沸石，必须使用有机模板，导致形成大量的污染废物，这对环境不友好。在2008年，我们展示了无有机模板合成铝硅酸盐Beta的第一个示例，其中完全避免了常规合成中氢氧化四乙铵的有机模板。然而，对于其他重要的基于铝磷酸盐的分子筛和纯硅沸石的无有机模板合成，它仍然面临着挑战。在这篇简短的评论中，它简要概述了无模板有机合成铝磷酸盐和硅铝磷酸盐分子筛以及纯硅沸石的最新进展，与在有机模板存在下合成的那些相比，它们是绿色且可持续的。