Porous organic polymers (POPs) are excellent adsorbent candidates owing to their high porosity, permanent pore, and well-designed structure. Ionic porous organic polymers (i-POPs) are a special type of POPs, which can greatly improve the capacity of guest molecules through electrostatic interactions. However, most reported i-POPs have shortcomings such as low porosity and high-cost synthesis procedure. With these considerations in mind, several ionic porous organic polymers (i-POP-BP-BPTMs) have been successfully designed and synthesized by using the commercial and simple-synthesized building units via a simple and cost-effective process. i-POP-BP-BPTMs indicated excellent porosity including the highest BET surface area (1491–1753 m² g⁻¹) and the best pore volume (2.19–2.94 cm³ g⁻¹) among most reported ionic POPs. Interestingly, i-POP-BP-BPTM was found to be highly effective in iodine vapor capture up to 415 wt%, which is higher than the value of all reported ionic POPs. These results offer a new way to design and construct functional ionic POPs.

多孔有机聚合物（POPs）由于具有高孔隙率，永久孔隙和精心设计的结构，因此是极好的吸附剂。离子多孔有机聚合物（i-POPs）是一种特殊的POPs，可通过静电相互作用极大地提高客体分子的容量。然而，大多数报道的i-POP具有诸如低孔隙率和高成本合成程序的缺点。考虑到这些考虑因素，通过使用商业和简单合成的建筑单元，通过简单且经济高效的方法，成功设计并合成了几种离子多孔有机聚合物（i-POP-BP-BPTM）。i-POP-BP-BPTMs显示出优异的孔隙率，包括最高的BET表面积（1491-1753 m ²  g ^-1）和最佳的孔体积（2.19-2.94 cm）在大多数报告的离子POP中为³  g ^-1）。有趣的是，发现i-POP-BP-BPTM在捕获高达415 wt％的碘蒸气中非常有效，这高于所有报道的离子POPs的值。这些结果提供了设计和构建功能性离子POP的新方法。