Water, Air, & Soil Pollution ( IF 2.9 ) Pub Date : 2020-07-21 , DOI: 10.1007/s11270-020-04787-5 Yueyang Xu , Zhaoping Zhong
Magnetic Co0.5Zn0.5Fe2O4 nanoparticles were prepared by the nitrate-alcohol-solution combustion and calcination technique. The morphology and composition of Co0.5Zn0.5Fe2O4 nanoparticles were characterized by the scanning electron microscopy (SEM), the transmission electron microscopy (TEM), the X-ray diffraction (XRD), the energy-dispersive spectroscopy (EDS), the vibrating sample magnetometer (VSM), the Fourier transform infrared spectrometer (FTIR), and the Brunauer-Emmett-Teller measurement (BET). The concentration of the ferric nitrate and the calcination temperature were the two key factors to the property of Co0.5Zn0.5Fe2O4 nanoparticles. To achieve greater adsorption capacity and durability of materials, magnetic Co0.5Zn0.5Fe2O4 nanoparticles calcined at 400 °C with ferric nitrate concentration of 0.84 M were employed to remove reactive red 2BF (RR-2BF). The pseudo-second-order kinetic model could be applied to describe the adsorption process of RR-2BF onto Co0.5Zn0.5Fe2O4 nanoparticles in the initial RR-2BF concentrations of 100–400 mg L−1, and the adsorption process could be fitted well by Langmuir model. The above adsorption experiments results suggested that the adsorption of RR-2BF onto Co0.5Zn0.5Fe2O4 nanoparticles was the monolayer adsorption mechanism. The effect of the dye solution pH on the adsorption process had been explored. At the same time, the removal efficiency for RR-2BF onto Co0.5Zn0.5Fe2O4 nanoparticles could maintain more than 72% after 10 cycles.
中文翻译:
活性红2BF在磁性Co 0.5 Zn 0.5 Fe 2 O 4纳米颗粒上的吸附机理
通过硝酸乙醇溶液燃烧煅烧技术制备了磁性Co 0.5 Zn 0.5 Fe 2 O 4纳米颗粒。通过扫描电子显微镜(SEM),透射电子显微镜(TEM),X射线衍射(XRD),能量色散谱(EDS)表征了Co 0.5 Zn 0.5 Fe 2 O 4纳米颗粒的形貌和组成。,振动样品磁力计(VSM),傅立叶变换红外光谱仪(FTIR)和Brunauer-Emmett-Teller测量(BET)。硝酸铁的浓度和煅烧温度是影响钴性能的两个关键因素。0.5 Zn 0.5 Fe 2 O 4纳米颗粒。为了获得更大的吸附能力和材料耐久性,采用在400°C下煅烧的硝酸铁浓度为0.84 M的磁性Co 0.5 Zn 0.5 Fe 2 O 4纳米颗粒去除活性红2BF(RR-2BF)。伪二级动力学模型可用于描述RR-2BF在初始RR-2BF浓度为100-400 mg L -1时对Co 0.5 Zn 0.5 Fe 2 O 4纳米颗粒的吸附过程。,吸附过程可以很好地拟合Langmuir模型。上述吸附实验结果表明,RR-2BF在Co 0.5 Zn 0.5 Fe 2 O 4纳米颗粒上的吸附是单层吸附机理。研究了染料溶液pH值对吸附过程的影响。同时,RR-2BF在Co 0.5 Zn 0.5 Fe 2 O 4纳米颗粒上的去除率在10个循环后可以保持72%以上。