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Arrayed Cobalt Phosphide Electrocatalyst Achieves Low Energy Consumption and Persistent H 2 Liberation from Anodic Chemical Conversion
Nano-Micro Letters ( IF 26.6 ) Pub Date : 2020-07-22 , DOI: 10.1007/s40820-020-00486-2 Kai Zhang 1, 2 , Gong Zhang 3 , Qinghua Ji 3 , Jiuhui Qu 3, 4 , Huijuan Liu 1, 3
中文翻译:
阵列式磷化钴电催化剂实现了低能耗和阳极化学转化过程中持久的H 2释放
更新日期:2020-07-22
Nano-Micro Letters ( IF 26.6 ) Pub Date : 2020-07-22 , DOI: 10.1007/s40820-020-00486-2 Kai Zhang 1, 2 , Gong Zhang 3 , Qinghua Ji 3 , Jiuhui Qu 3, 4 , Huijuan Liu 1, 3
Affiliation
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A template approach for the synthesis of porous cobalt phosphide nanoarrays (Co2P/CoP NAs) is reported, which exhibits superior electrocatalytic activity and stability toward charge storage and hydrogen evolution.
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Using Co2P/CoP NAs as a charge mediator, the H2 and O2 evolution of alkaline water electrolysis is separated effectively in time, thereby achieving a membrane-free pathway for H2 purification.
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Introduction of easily oxidized chemicals to replace water oxidation triggers a low energy consumption path toward H2 purification.
中文翻译:
阵列式磷化钴电催化剂实现了低能耗和阳极化学转化过程中持久的H 2释放
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报道了用于合成多孔磷化钴纳米阵列(Co 2 P / CoP NAs)的模板方法,该方法显示出优异的电催化活性以及对电荷存储和析氢的稳定性。
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使用Co 2 P / CoP NAs作为电荷介体,可以及时有效地分离出碱性水电解中的H 2和O 2析出物,从而实现了无膜的H 2纯化途径。
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引入易氧化的化学物质代替水氧化触发了通往H 2净化的低能耗途径。