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Investigation of the effect of temperature on aggregation behaviour and thermodynamic properties of Ornithine monohydrochloride in aqueous and aqueous dextrose and urea solutions
The Journal of Chemical Thermodynamics ( IF 2.6 ) Pub Date : 2020-12-01 , DOI: 10.1016/j.jct.2020.106254
Nikhat G. Sheikh , Vijay M. Tangde , Sudhakar S. Dhondge , Alka S. Dhondge , Niraj T. Khaty

Abstract In this communication for the first time, we report the density ρ and speed of sound u of aqueous solution of Ornithine monohydrochloride (Ornithine·HCl) and Ornithine monohydrochloride (Ornithine·HCl) in aqueous 0.06 mol·kg−1 urea and aqueous 0.06 mol·kg−1 dextrose at T = (288.15, 293.15, 298.15, 303.15, 308.15, 313.15 and 318.15) K within the concentration range of (0.02 to 0.2) mol·kg−1. From the experimental data of density (ρ) and speed of sound (u) the various derived parameters such as apparent molar volume of solute (Vϕ) limiting apparent molar volume of solute V ϕ 0 , limiting apparent molar volume of transfer (ΔtrVϕ0), limiting apparent molar expansivity E ϕ 0 , thermal expansion coefficient (α*), second derivative of limiting apparent molar volume ∂ 2 V ϕ 0 / ∂ T 2 , isentropic compressibility κs, apparent molar compression (Ks,ϕ), limiting apparent molar compression of solute K S , ϕ 0 , apparent molar isentropic compression of transfer Δ tr K S , ϕ 0 and hydration number (nH) have been calculated.

中文翻译:

研究温度对单盐酸盐鸟氨酸在葡萄糖和尿素水溶液和水溶液中的聚集行为和热力学性质的影响

摘要 在这篇通讯中,我们首次报道了鸟氨酸单盐酸盐 (Ornithine·HCl) 和鸟氨酸单盐酸盐 (Ornithine·HCl) 在 0.06 mol·kg−1 尿素水溶液和 0​​.06 水溶液中的密度 ρ 和声速 u mol·kg-1 葡萄糖在 T = (288.15, 293.15, 298.15, 303.15, 308.15, 313.15 和 318.15) K 浓度范围内 (0.02 至 0.2) mol·kg-1。从密度 (ρ) 和声速 (u) 的实验数据得出各种衍生参数,例如溶质的表观摩尔体积 (Vϕ) 限制溶质的表观摩尔体积 V ϕ 0 、限制转移的表观摩尔体积 (ΔtrVϕ0),极限表观摩尔膨胀率 E ϕ 0 ,热膨胀系数 (α*),极限表观摩尔体积的二阶导数 ∂ 2 V ϕ 0 / ∂ T 2 ,等熵压缩率 κs,表观摩尔压缩 (Ks,
更新日期:2020-12-01
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