The recent focus of media and governments on renewability, green chemistry, and circular economy has led to a surge in the synthesis of renewable monomers and polymers. In this review, focussing on renewable monomers for reversible deactivation radical polymerizations (RDRP), it is highlighted that for the majority of the monomers and polymers reported, the claim to renewability is not always accurate. By closely examining the sustainability of synthetic routes and the renewability of starting materials, fully renewable monomers are identified and discussed in terms of sustainability, polymerization behavior, and properties obtained after polymerization. The holistic discussion considering the overall preparation process of polymers, that is, monomer syntheses, origin of starting materials, solvents used, the type of RDRP technique utilized, and the purification method, allows to highlight certain topics which need to be addressed in order to progress toward not only (partially) renewable, but sustainable monomers and polymers using RDRPs.

中文翻译：

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可持续可逆失活自由基聚合的进展。

媒体和政府最近对可再生性，绿色化学和循环经济的关注导致可再生单体和聚合物的合成激增。在这篇综述中，着眼于可逆性钝化自由基聚合（RDRP）的可再生单体，强调了对于报告的大多数单体和聚合物，可再生性的主张并不总是准确的。通过仔细检查合成路线的可持续性和原材料的可更新性，可以在可持续性，聚合行为和聚合后获得的性能方面鉴定和讨论完全可再生的单体。考虑到聚合物的整体制备过程的整体讨论，即单体合成，起始原料的来源，所用溶剂，所用RDRP技术的类型，