Abstract

The reaction of 1,3-dehydroadamantane with alkylbenzenes was studied for the first time. It involved the C–H bond of the alkyl substituent in the α-position with respect to the aromatic ring. The proposed radical mechanism of the reaction was confirmed by the isolation of 1,1′-biadamantane and 1,2-diphenylethane derivatives. Difficultly accessible (adamantan-1-ylmethyl)arenes were synthesized in 53–78% yields.

中文翻译：

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四环[3.3.1.1 3,7 .0 1,3]癸烷（1,3-脱氢金刚烷）的化学转化：IX。与炔烃的非催化反应

摘要

首次研究了1,3-脱氢金刚烷与烷基苯的反应。它涉及相对于芳香环的α位烷基取代基的CH键。通过分离1,1'-双金刚烷和1,2-二苯乙烷衍生物，证实了所提出的自由基反应机理。难以合成的（金刚烷-1-基甲基）芳烃的合成产率为53-78％。