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Coordination chemistry of anticrowns. Synthesis and structure of the binuclear complex of perfluorinated three-mercury anticrown (o-F6Hg)3 with 1,2-dichloroethane
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-06-01 , DOI: 10.1007/s11172-020-2872-x
K. I. Tugashov , S. M. Yunusov , E. S. Kalyuzhnaya , F. M. Dolgushin , I. A. Tikhonova , V. B. Shur

The reaction of perfluorinated three-mercury anticrown (o-C6F4Hg)3 (1) with 1,2-dichloroethane (DCE) affords the complex {[(o-C6F4Hg)3]2(ClCH2CH2Cl)}(2) containing two anticrown molecules per DCE molecule. According to the X-ray diffraction data, the DCE molecule in complex 2 acts as a bridge between molecules 1, each DCE chlorine atom being coordinated to a single mercury center of the neighboring anticrown molecules.

中文翻译:

反冠的配位化学。全氟三汞反冠(o-F6Hg)3与1,2-二氯乙烷双核络合物的合成与结构

全氟三汞抗冠 (o-C6F4Hg)3 (1) 与 1,2-二氯乙烷 (DCE) 反应得到包含两个抗冠分子的复合物 {[(o-C6F4Hg)3]2(ClCH2CH2Cl)}(2)每个 DCE 分子。根据 X 射线衍射数据,配合物 2 中的 DCE 分子充当分子 1 之间的桥梁,每个 DCE 氯原子与相邻反冠分子的单个汞中心配位。
更新日期:2020-06-01
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