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Mechanical, thermal, melt-flow and morphological characterizations of bentonite-filled ABS copolymer
Rapid Prototyping Journal ( IF 3.9 ) Pub Date : 2020-06-17 , DOI: 10.1108/rpj-12-2019-0321
Laylay Mustafa Alhallak , Seha Tirkes , Umit Tayfun

This study aims to investigate the mechanical, thermal, melt-flow and morphological behavior of acrylonitrile-butadiene-styrene (ABS)-based composites after bentonite inclusions. Melt mixing is the most preferred production method in industrial scale and basically it has very near processing parameters compared to 3D printing applications. Rheological parameters of ABS and its composites are important for 3D applications. Melt flow behavior of ABS effects the fabrication of 3D printed product at desired levels. Shear thinning and non-Newtonian viscosity characteristics of ABS make viscosity control easier and more flexible for several processing techniques including injection molding, compression molding and 3D printing.,ABS copolymer was reinforced with bentonite mineral (BNT) at four different loading ratios of 5%, 10%, 15% and 20%. ABS/BNT composites were fabricated by lab-scale micro-compounder followed by injection molding process. Mechanical, thermo-mechanical, thermal, melt-flow and morphological properties of composites were investigated by tensile, hardness and impact tests, dynamic mechanical analysis (DMA), thermo-gravimetric analysis (TGA), melt flow index (MFI) test and scanning electron microscopy (SEM), respectively.,Mechanical tests revealed that tensile strength, elongation and hardness of ABS were enhanced as BNT content increased. Glass transition temperature and storage modulus of ABS exhibited increasing trend with the additions of BNT. However, impact strength values dropped down with BNT inclusion. According to MFI test measurements, BNT incorporation displayed no significant change for MFI value of ABS. Homogeneous dispersion of BNT particles into ABS phase was deduced from SEM micrographs of composites. Loading ratio of 15% BNT was remarked as the most suitable candidate among fabricated ABS-based composites according to findings.,The advanced mechanical properties and easy processing characteristics are the reasons for usage of ABS as an engineering plastic. Owing to the increase in its usage for 3D printing technology, the ABS became popular in recent years. The utilization of ABS in this technology is in filament form with various colors and dimensions. This is because of its proper rheological features.,Melt-mixing technique was used as preparation of composites, as this processing method is widely applied in industry. This method is also providing similar processing methodology with 3D printing technology.,According to the literature survey, to the best of the authors’ knowledge, this study is the first research work regarding the melt-flow performance of ABS-based composites to evaluate their 3D printing applications and processability. ABS and BNT containing composites were characterized by tensile, impact and shore hardness tests, DMA, TGA), MFI test and SEM techniques.

中文翻译:

膨润土填充 ABS 共聚物的机械、热、熔体流动和形态表征

本研究旨在研究膨润土夹杂物后丙烯腈-丁二烯-苯乙烯 (ABS) 基复合材料的机械、热、熔体流动和形态行为。熔融混合是工业规模最优选的生产方法,与 3D 打印应用相比,它基本上具有非常接近的加工参数。ABS 及其复合材料的流变参数对于 3D 应用很重要。ABS 的熔体流动行为会以所需的水平影响 3D 打印产品的制造。ABS 的剪切稀化和非牛顿粘度特性使粘度控制更容易、更灵活,适用于包括注塑、压缩成型和 3D 打印在内的多种加工技术。, ABS 共聚物用膨润土矿物 (BNT) 以四种不同的 5% 负载率增强、10%、15% 和 20%。ABS/BNT 复合材料是通过实验室规模的微复合材料和注塑成型工艺制造的。通过拉伸、硬度和冲击试验、动态力学分析 (DMA)、热重分析 (TGA)、熔体流动指数 (MFI) 测试和扫描研究了复合材料的机械、热机械、热、熔体流动和形态特性电子显微镜(SEM)分别表明,力学测试表明,随着 BNT 含量的增加,ABS 的拉伸强度、伸长率和硬度均提高。随着BNT的加入,ABS的玻璃化转变温度和储能模量呈现增加趋势。然而,由于包含 BNT,冲击强度值下降。根据 MFI 测试测量,BNT 掺入对 ABS 的 MFI 值没有显着变化。从复合材料的 SEM 显微照片推断 BNT 颗粒均匀分散到 ABS 相中。根据研究结果,15% BNT 的负载率被认为是制造的 ABS 基复合材料中最合适的候选者。先进的机械性能和易加工特性是 ABS 用作工程塑料的原因。由于 3D 打印技术的使用增加,近年来 ABS 开始流行。ABS 在该技术中的使用是具有各种颜色和尺寸的细丝形式。这是因为它具有适当的流变特性。熔融混合技术被用于制备复合材料,因为这种加工方法在工业中得到了广泛的应用。这种方法也提供了与 3D 打印技术类似的处理方法。根据文献调查,据作者所知,这项研究是关于 ABS 基复合材料的熔体流动性能以评估其 3D 打印应用和可加工性的第一项研究工作。包含 ABS 和 BNT 的复合材料通过拉伸、冲击和肖氏硬度测试、DMA、TGA)、MFI 测试和 SEM 技术进行表征。
更新日期:2020-06-17
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