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Effect of plasma gas and Ar incorporation on the shear strength between carbon fiber-reinforced thermoplastic polymer and Al
Composites Part A: Applied Science and Manufacturing ( IF 8.7 ) Pub Date : 2020-07-12 , DOI: 10.1016/j.compositesa.2020.106041
Yoon Sang Kim , Unseok Jung , Sunwoong Choi , Yong Chae Jung , Hun-Su Lee , Jaewoo Kim

With the growing industrial demand for carbon fiber-reinforced thermoplastic polymers (CFRTPs), there is an urgent need to improve their adhesion to conventional metal substrates. In this study, the effect of plasma gas and Ar incorporation on the shear strength between CFRTP and Al was examined. Although NH3 plasma had a greater effect on the surface properties of CFRTP than O2 plasma, the incorporation of Ar into O2 plasma showed a 280% improvement in shear strength relative to the untreated reference. Plasma treatment proved effective only on the CFRTP surface, with the failure mode switching from adhesive to substrate failure. Spectroscopic analyses revealed that functional groups like CO, OCO, or H2NC were either newly generated or their quantity increased on the CFRTP surface. Additionally, CFRTP itself acts as an oxygen source, and its shear strength improved significantly under Ar plasma treatment, even without external O2 supply.



中文翻译:

等离子体气体和Ar的掺入对碳纤维增强热塑性聚合物和Al剪切强度的影响

随着工业上对碳纤维增强热塑性聚合物(CFRTP)的需求不断增长,迫切需要提高其对常规金属基材的粘合力。在这项研究中,研究了等离子体气体和Ar掺入对CFRTP和Al之间的剪切强度的影响。尽管NH 3等离子体对CFRTP的表面性能的影响大于O 2等离子体,但将Ar掺入O 2等离子体相对于未处理的参比样品,剪切强度提高了280%。等离子体处理仅在CFRTP表面上证明有效,并且失效模式从粘合剂转变为基材失效。光谱分析表明,官能团如C O,O C O或H 2N C要么是新产生的,要么在CFRTP表面增加了数量。另外,CFRTP本身可作为氧气源,即使没有外部O 2供给,其在Ar等离子体处理下的剪切强度也显着提高。

更新日期:2020-07-17
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