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3D carbon framework-supported FeSe for high-performance potassium ion batteries
Sustainable Energy & Fuels ( IF 5.6 ) Pub Date : 2020-07-13 , DOI: 10.1039/d0se00146e
Jianhua Deng 1, 2, 3, 4 , Xianglong Huang 1, 2, 3, 4 , Wei Gao 1, 2, 3, 4 , Hongdong Liu 3, 4, 5, 6 , Maowen Xu 1, 2, 3, 4
Affiliation  

FeSe@C with a 3D porous interconnected carbon framework is used as the anode for potassium ion batteries (PIBs). FeSe@C has a relatively large specific surface area and a superior microporous and mesoporous structure, thus facilitating the storage and transportation of potassium ions. When tested in PIBs as an anode, FeSe@C shows good specific capacity of 298.5 mA h g−1 after 200 cycles at 500 mA g−1, thus indicating good cycle stability. In addition, a possible potassium storage mechanism is explored. Moreover, the diffusion coefficient of potassium ions (DK) of FeSe@C is 1.67 × 10−10 cm2 s−1 is calculated. Therefore, the FeSe@C composite is expected to become the next-generation anode material for PIBs.

中文翻译:

3D碳骨架支持的FeSe用于高性能钾离子电池

具有3D多孔互连碳骨架的FeSe @ C用作钾离子电池(PIB)的阳极。FeSe @ C具有相对较大的比表面积和优异的微孔和中孔结构,因此有利于钾离子的储存和运输。当在作为阳极的PIB中进行测试时,FeSe @ C在500 mA g -1下200次循环后显示出298.5 mA hg -1的良好比电容,因此表明良好的循环稳定性。另外,探索了可能的钾存储机制。此外,钾离子(的扩散系数d ķ FESE的)@ C是1.67×10 -10厘米2个小号-1计算。因此,FeSe @ C复合材料有望成为PIB的下一代阳极材料。
更新日期:2020-08-25
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