A series of glasses with the compositions of 10NaF-(90-x) NaPO₃-xYF₃ (x = 5, 10, 15 and 20 mol%) were prepared via the conventional melt-quenching method. The structures of these glasses were characterized by multiple advanced solid-state nuclear magnetic resonance (SSNMR) techniques. Multiple phosphorus species Q^m_nY were resolved at atomic level. Here, the value m and n denote the number of P–O–P bonds and the number of Y³⁺ ion bounding to phosphorus oxygen tetrahedron, respectively, which were identified by two dimensional (2D) J-resolved spectroscopy. ¹⁹F MAS spectra, ¹⁹F↔²³Na and ¹⁹F↔³¹P rotational echo double resonance (REDOR) prove that F⁻ions are involved into the glass networks through Y-F•••Na and P-F•••Na linkages. The ³¹P {¹⁹F} J-coupling based heteronuclear multiple quantum coherence (J-HMQC) spectrum proves that F⁻ ions selectively connect with Q¹ species. F⁻ ions show significant preference to connecting with Y³⁺ over P⁵⁺.

 通过常规的熔融淬火方法制备了一系列具有10NaF-（90-x）NaPO ₃ -xYF ₃（x＝5、10、15和20mol％）组成的玻璃。这些玻璃的结构通过多种先进的固态核磁共振（SSNMR）技术进行了表征。在原子水平上解析了多种磷物质Q ^m _nY。此处，m和n分别表示通过二维（2D）J解析光谱确定的与磷氧四面体键合的P–O–P键数和Y ³⁺离子数。¹⁹ ˚FMAS光谱，¹⁹ F↔ ²³ Na和¹⁹ F↔ ³¹ P旋转回波双共振（REDOR）证明˚F ^-离子参与到通过YF•••Na和PF•••娜键的玻璃网络。的³¹ p { ¹⁹ F} Ĵ -耦合基于异核多量子相干（Ĵ -HMQC）光谱证明˚F ^-离子选择性具有Q连接¹种。˚F ^-离子显示显著偏好为Y连接³⁺用P ⁵⁺。