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Enhancement of hydroxyapatite formation on titanium surface by alkali heat treatment combined with induction heating and acid etching
Surface & Coatings Technology ( IF 5.4 ) Pub Date : 2020-07-08 , DOI: 10.1016/j.surfcoat.2020.126173
Xingchuan Zhao , Xiaojian Ren , Changzheng Wang , Baoxu Huang , Jie Ma , Bo Ge , Zhengfeng Jia , Yuchao Li

Pure titanium (Ti) often exhibits biologically inert performance in clinical medicine due to the occurrence of surface passivation. Surface modification is crucial to improve the biological activity and long-term stability of Ti. In this research, Induction heating + acid etching + alkali heat (IHT + AET + AHT) treatment methods were used to rapidly fabricate a biologically activated structure on the Ti surface. The effects of IHT + AET + AHT on the microstructure, phase composition, properties, and formation mechanisms of the coatings were investigated. The results showed that a fine and uniform porous network composite coating of sodium titanate and rutile TiO2 was formed by IHT + AET + AHT methods, which showed good adhesion and corrosion resistance. Compared with AHT, IHT + AET + AHT can significantly reduce the pore size of sodium titanate from 300-350 nm to 80–100 nm. The IHT + AET + AHT coating has a good ability to induce hydroxyapatite (HA) formation in simulated body fluid (SBF). Moreover, the HA formed on the IHT + AET + AHT coating exhibits excellent long-term stability.



中文翻译:

碱热处理与感应加热和酸蚀相结合可增强钛表面羟基磷灰石的形成

由于表面钝化的发生,纯钛(Ti)在临床医学中通常表现出生物学惰性。表面改性对于提高Ti的生物活性和长期稳定性至关重要。在这项研究中,感应加热+酸蚀刻+碱热(IHT + AET + AHT)处理方法被用来在Ti表面上快速制造生物活化结构。研究了IHT + AET + AHT对涂层的微观结构,相组成,性能和形成机理的影响。结果表明,钛酸钠和金红石型TiO 2细密均匀的多孔网络复合涂层通过IHT + AET + AHT方法形成的涂层,具有良好的附着力和耐腐蚀性。与AHT相比,IHT + AET + AHT可以将钛酸钠的孔径从300-350 nm减小到80-100 nm。IHT + AET + AHT涂层具有良好的诱导模拟体液(SBF)中羟基磷灰石(HA)形成的能力。此外,在IHT + AET + AHT涂层上形成的HA表现出出色的长期稳定性。

更新日期:2020-07-08
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