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Graphene oxide-manganese ferrite (GO-MnFe2O4) nanocomposite: One-pot hydrothermal synthesis and its use for adsorptive removal of Pb2+ ions from aqueous medium
Journal of Molecular Liquids ( IF 6 ) Pub Date : 2020-07-07 , DOI: 10.1016/j.molliq.2020.113769
Monu Verma , Ashwani Kumar , Krishna Pal Singh , Ravi Kumar , Vinod Kumar , Chandra Mohan Srivastava , Varun Rawat , Gyandeshwar Rao , Sujata Kumari , Pratibha Sharma , Hyunook Kim

Herein, we showed that the graphene oxide with manganese ferrite (GO-MnFe2O4) possess great adsorption properties for the selective Pb2+ ions removal from the aqueous medium. Nanocomposite adsorbent was developed by one-pot hydrothermal method, using graphene oxide as a supporting material to minimize the aggregation of MnFe2O4. Also, GO possesses important role in the adsorption mechanism of Pb2+ through electrostatic/ionic interactions. The characterizations such as FT-IR, XPS, P-XRD, FE-SEM, and BET of the synthesized nanocomposite were carried out to assess the different properties such as functionalities, crystallinity, morphology, and surface area value, respectively. Thereafter, the adsorption performance of GO-MnFe2O4 nanocomposite was tested for the Pb2+ at various adsorption parameters including to contact time, solution pH, adsorbent dose, and concentration of initial Pb2+ in order to measure the optimum adsorption condition. Kinetic experiments suggest that the equilibrium attained in 30 min and followed a pseudo-second-order kinetic model. Adsorption isotherm model followed to Langmuir isotherms and gives a maximum adsorption capacity of 621.11 mg/g. The reusability tests exhibited good durability and good efficiency for repeated Pb2+ adsorptions with GO-MnFe2O4 nanocomposite. These results demonstrated that the GO-MnFe2O4 nanocomposite may be an attractive adsorbent having low-cost for the effectively Pb+2 removal of from the polluted water.



中文翻译:

氧化石墨烯-锰铁氧体(GO-MnFe 2 O 4)纳米复合材料:一锅水热合成及其在水介质中吸附去除Pb 2+离子中的用途

在此,我们显示了带有锰铁氧体的氧化石墨烯(GO-MnFe 2 O 4)对于从水性介质中选择性去除Pb 2+离子具有很大的吸附性能。通过一锅水热法开发纳米复合吸附剂,使用氧化石墨烯作为载体材料,以最大程度地减少MnFe 2 O4的聚集。另外,GO在Pb 2+的吸附机理中也起重要作用通过静电/离子相互作用。对合成的纳米复合材料进行了FT-IR,XPS,P-XRD,FE-SEM和BET等表征,以分别评估其不同的性能,例如功能性,结晶度,形态和表面积值。此后,在接触时间,溶液pH,吸附剂剂量和初始Pb 2+浓度等各种吸附参数下,测试了GO-MnFe 2 O 4纳米复合材料对Pb 2+的吸附性能。为了测量最佳的吸附条件。动力学实验表明,在30分钟内达到了平衡,并遵循了伪二级动力学模型。吸附等温线模型遵循Langmuir等温线,最大吸附容量为621.11 mg / g。可重复使用性测试对于GO-MnFe 2 O 4纳米复合材料的Pb 2+重复吸附表现出良好的耐久性和效率。这些结果表明,GO-MnFe 2 O 4纳米复合材料可能是一种吸引人的吸附剂,其具有从污染水中有效去除Pb +2的低成本。

更新日期:2020-07-14
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