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Development of watermelon rind derived activated carbon/manganese ferrite nanocomposite for cleaner desalination by capacitive deionization
Journal of Cleaner Production ( IF 11.1 ) Pub Date : 2020-07-07 , DOI: 10.1016/j.jclepro.2020.122626
K. Rambabu , G. Bharath , Abdul Hai , Shaohong Luo , Kin Liao , Mohammad Abu Haija , Fawzi Banat , Mu. Naushad

Capacitive deionization (CDI) is one of the most efficient and emerging techniques for water desalination applications. This work reports the development, characterization and CDI studies of watermelon derived activated carbon (WMAC) and its MnFe2O4 composite (WMAC/MnFe2O4) for NaCl desalination. WMAC was prepared through single-step low-temperature pyrolysis by H3PO4 activation. Facile synthesis of spinel MnFe2O4 nanoparticles on WMAC surface was performed through the hydrothermal technique. Morphological, textural and physico/electro–chemical analysis showed the effect of MnFe2O4 incorporation on WMAC. The nanocomposite possessed definite crystallites, low structural disorders and sufficient magnetization for electrochemical applications. Also, the nanocomposite was dominantly composed of mesopores with a specific surface area of 483 m2/g., The high specific capacitance value of 425 F/g (scan rate – 10 mV/s) along with better stability and low charge resistance, confirmed the suitability of WMAC/MnFe2O4 as an efficient electrode material for CDI applications. NaCl removal studies using WMAC/MnFe2O4 showed an electrosorption capacity of 29 mg/g for the nanocomposite, with rapid desalination and good recyclability. A plausible mechanism of salt adsorption and desorption is also presented. WMAC/MnF2O4 exhibited significant application potential for the industrial desalination.



中文翻译:

西瓜皮衍生的活性炭/锰铁氧体纳米复合材料的开发,用于通过电容去离子清洁除盐剂

电容去离子(CDI)是用于水脱盐应用的最有效和新兴的技术之一。这项工作报告了西瓜衍生的活性炭(WMAC)及其用于NaCl脱盐的MnFe 2 O 4复合材料(WMAC / MnFe 2 O 4)的开发,表征和CDI研究。WMAC是通过H 3 PO 4活化通过一步低温热解制备的。通过水热技术在WMAC表面方便地合成了尖晶石MnFe 2 O 4纳米颗粒。形态,结构和物理/电化学分析表明MnFe 2 O 4的作用加入WMAC。该纳米复合材料具有确定的微晶,低结构紊乱和足够的磁化强度,可用于电化学应用。此外,纳米复合材料主要由比表面积为483 m 2 / g的中孔组成,比电容值为425 F / g(扫描速率– 10 mV / s),具有更高的稳定性和较低的抗充电性,证实了WMAC / MnFe 2 O 4作为CDI应用的有效电极材料的适用性。使用WMAC / MnFe 2 O 4去除NaCl的研究纳米复合材料的电吸附容量为29 mg / g,具有快速脱盐和良好的可回收性。还提出了合理的盐吸附和解吸机理。WMAC / MnF 2 O 4在工业脱盐方面显示出巨大的应用潜力。

更新日期:2020-07-07
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