In this minireview, weak interactions that occur in supramolecular polymers are discussed. Combination of weak and strong interactions plays an important role in the construction of supramolecular polymers. It is beneficial to separate the contributions of the weak interactions, as well as each solvent effect on the weak interactions. However, it is generally difficult to observe each solvent effect separately at work in each interaction. Small molecular probes are useful to estimate the contributions of the weak interaction. But, the results should be treated with caution when applied to supramolecular polymer systems. To overcome the problems, a new solvent parameter, solvation ability (SA), is introduced, which was determined on the balance point of extended and stacked forms of porphyrin‐based interconvertible supramolecular polymers.

中文翻译：

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超分子聚合物中弱相互作用的溶剂效应：小分子探针和超分子聚合物之间的差异。

在本篇综述中，讨论了在超分子聚合物中发生的弱相互作用。弱相互作用和强相互作用的组合在超分子聚合物的构造中起重要作用。分离弱相互作用的贡献以及每种溶剂对弱相互作用的作用是有益的。但是，通常很难在每个相互作用的工作中分别观察每种溶剂的作用。小分子探针可用于评估弱相互作用的作用。但是，将结果应用于超分子聚合物体系时应谨慎对待。为了克服这些问题，引入了一个新的溶剂参数，溶剂化能力（SA），该参数是在基于卟啉的可相互转化的超分子聚合物的扩展形式和堆积形式的平衡点上确定的。