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Microstructure and oxidation behaviour of Pt modified NiCrAlYSi coating on a Ni-based single crystal superalloy
Surface & Coatings Technology ( IF 5.4 ) Pub Date : 2020-07-06 , DOI: 10.1016/j.surfcoat.2020.126164
J. Sun , H. Xiao , W. Li , S.B. Liu , L.B. Fu , S.M. Jiang

In this study, the Pt + NiCrAlYSi coating and NiCrAlYSi+Pt coating were produced onto the Ni-based single crystal superalloy by using the arc ion plating (AIP) and electroplating. For the Pt + NiCrAlYSi coating, the Pt mainly distributed in substrate and the bottom of coating, while the Pt primarily located at the outer part of NiCrAlYSi+Pt coating. After isothermal oxidation at 1100 °C, the weight gains for the NiCrAlYSi coating, Pt + NiCrAlYSi coating and NiCrAlYSi+Pt coating were 1.81 mg/cm2, 1.68 mg/cm2 and 1.37 mg/cm2, respectively. The parabolic rate constant of the NiCrAlYSi+Pt coating was 6.2 × 10−3 mg2 cm−4 h−1, which was the smallest among three kinds of coatings. The mass of spalled oxides for the NiCrAlYSi coating, Pt + NiCrAlYSi coating and NiCrAlYSi+Pt coating were 2.07 mg/cm2, 0.937 mg/cm2 and 0.801 mg/cm2 after cyclic oxidation at 1150 °C. So, the addition of Pt in the NiCrAlYSi coating can significantly improve the adhesion of alumina scale. The oxidation test results indicated that the NiCrAlYSi+Pt coating showed the best oxidation resistance. Some Pt-rich particles were observed on the surface of the NiCrAlYSi+Pt coating after 1 cycle at 1150 °C. The enrichment of Pt on the outer part of NiCrAlYSi+Pt coating can increase the out diffusion flux of Al and promote the fast formation of pure Al2O3 at the early stage of oxidation.



中文翻译:

镍基单晶高温合金上Pt修饰NiCrAlYSi涂层的组织和氧化行为

在这项研究中,通过使用电弧离子镀(AIP)和电镀在Ni基单晶高温合金上生产了Pt + NiCrAlYSi涂层和NiCrAlYSi + Pt涂层。对于Pt + NiCrAlYSi涂层,Pt主要分布在基材和涂层底部,而Pt主要位于NiCrAlYSi + Pt涂层的外部。在1100等温氧化之后℃下,对于NiCrAlYSi涂层的重量增加,铂+ NiCrAlYSi涂层和NiCrAlYSi +铂涂层分别为1.81毫克/平方厘米2,1.68毫克/平方厘米2和1.37毫克/平方厘米2分别。NiCrAlYSi + Pt涂层的抛物线速率常数为6.2×10 -3  mg 2  cm -4  h -1,这是三种涂料中最小的。为NiCrAlYSi涂层,铂+ NiCrAlYSi涂层和NiCrAlYSi +铂涂层剥落氧化物的质量分别为2.07毫克/平方厘米2,0.937毫克/平方厘米2和0.801毫克/平方厘米2后,在1150循环氧化℃。因此,在NiCrAlYSi涂层中添加Pt可以显着提高氧化铝鳞片的附着力。氧化测试结果表明,NiCrAlYSi + Pt涂层具有最佳的抗氧化性。在1150°C下经过1个循环后,在NiCrAlYSi + Pt涂层的表面上观察到一些富含Pt的颗粒。NiCrAlYSi + Pt涂层外部富集Pt可以增加Al的向外扩散通量并促进纯Al 2 O 3的快速形成 在氧化的初期。

更新日期:2020-07-06
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