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Recent Progress of Palladium-Based Electrocatalysts for the Formic Acid Oxidation Reaction
Energy & Fuels ( IF 5.3 ) Pub Date : 2020-07-03 , DOI: 10.1021/acs.energyfuels.0c01820
Tao Shen 1 , Jingjing Zhang 1 , Ke Chen 1 , Shaofeng Deng 1 , Deli Wang 1
Affiliation  

Direct formic acid fuel cells (DFAFCs) are considered as one of the promising energy conversion devices. In recent years, Pd-based nanomaterials have attracted widespread attention for the anodic formic acid oxidation reaction (FAOR) due to high catalytic activity and antipoisoning capability. Among large amounts of reports, several factors contribute to the FAOR performance concurrently. In this review, the effects which influence the catalytic activity toward the FAOR are concluded and the deactivation mechanisms are compared. Besides, the strategies for removal/restriction of adsorbed CO species, which poison the active sites, are discussed. Several strategies, including the morphology tailoring, alloying with other elements, and optimizing the support, are presented comprehensively. Finally, we summarize these works and provide some suggestions for the future work on the FAOR catalysts.

中文翻译:

甲酸氧化反应中钯基电催化剂的最新进展

直接甲酸燃料电池(DFAFC)被认为是有前途的能量转换装置之一。近年来,基于Pd的纳米材料由于其高的催化活性和抗中毒能力而引起了阳极甲酸氧化反应(FAOR)的广泛关注。在大量报告中,有几个因素同时影响了粮农组织驻国家代表的绩效。在这篇综述中,总结了影响对FAOR催化活性的作用,并比较了失活机理。此外,还讨论了去除/限制吸附CO种类的策略,这些物质会毒化活性部位。全面介绍了几种策略,包括形态定制,与其他元素合金化以及优化支撑。最后,
更新日期:2020-08-20
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