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Effect of introducing varying amounts of polydopamine particles into different concentrations of polyethersulfone solution on the performance of resultant mixed-matrix membranes intended for dye separation
Journal of Polymer Research ( IF 2.8 ) Pub Date : 2020-07-05 , DOI: 10.1007/s10965-020-02174-6
Micah Belle Marie Yap Ang , Hazel Lynn C. Maganto , Charelle Rose M. Macni , Alvin R. Caparanga , Shu-Hsien Huang , Kueir-Rarn Lee , Juin-Yih Lai

In this study, polydopamine (PDA) particles were embedded into polyethersulfone (PES) membrane through wet-phase separation. We considered two concentration of PES solution—17 and 19 wt%. Adding different concentration of PDA (0–0.7 wt%) into the two solutions revealed an opposite effect on the characteristic and performance of the membrane. Incorporating PDA particles in 17 wt% PES solution was resulted in a decreased in pure water flux, and increased in dye rejection; Whereas, incorporating PDA particles in 19 wt% PES solution boosted the pure water flux with keep dye rejection of ~99.0%. At the optimum concentration of 0.5 wt% PDA added to 19 wt% PES solution, the following dye rejections were obtained: RMethylene Blue = 99.90 ± 1.45%; RProcion Blue H-5R = 98.33 ± 0.57%; RDirect Red 23 = 99.90 ± 1.82%; RBrilliant Blue = 99.90 ± 0.94%; RRose Bengal = 99.90 ± 0.0%; RDirect Red 80 = 99.12 ± 0.41%; for the salt rejections: (RNaCl = 10.59 ± 5.23%; RNa2SO4 = 8.87 ± 4.99%; RMgCl2 = 10.45 ± 6.85%; RMgSO4 = 10.02 ± 3.87%). This shows that the selectivity of the fabricated membrane towards different dyes and common inorganic salts is high. PDA is a favorable option for fabricating membranes for dye desalination under appropriate PES concentration.



中文翻译:

将不同量的聚多巴胺颗粒引入不同浓度的聚醚砜溶液中对所得的用于染料分离的混合基质膜的性能的影响

在这项研究中,聚多巴胺(PDA)颗粒通过湿相分离嵌入到聚醚砜(PES)膜中。我们考虑了两种浓度的PES溶液-17和19 wt%。在两种溶液中添加不同浓度的PDA(0–0.7 wt%),对膜的特性和性能产生相反的影响。将PDA颗粒掺入17 wt%的PES溶液中会导致纯水通量下降,并增加染料截留率。而在19 wt%的PES溶液中掺入PDA颗粒可提高纯净水通量,并保持约99.0%的染料截留率。在添加到19 wt%PES溶液中的0.5 wt%PDA的最佳浓度下,获得了以下染料排斥反应:R亚甲基蓝 = 99.90±1.45%;R Procion蓝H-5R  = 98.33±0.57%; [R直接红23  = 99.90±1.82%; R亮蓝色 = 99.90±0.94%; R玫瑰红 = 99.90±0.0%; R直接红80  = 99.12±0.41%; 对于除盐率:(R NaCl  = 10.59±5.23%; R Na2SO4  = 8.87±4.99%; R MgCl2  = 10.45±6.85%; R MgSO4  = 10.02±3.87%)。这表明制造的膜对不同的染料和常见的无机盐的选择性高。PDA是在适当的PES浓度下制造用于染料脱盐的膜的理想选择。

更新日期:2020-07-05
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