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Sulfoxide Reduction/C(sp3)-S Metathesis Cascade in Ionic Liquid.
Organic Letters ( IF 5.2 ) Pub Date : 2020-07-02 , DOI: 10.1021/acs.orglett.0c02089
Chenjing Liu 1 , Dengfeng Chen 1 , Yuanyuan Fu 1 , Fei Wang 1 , Jinyue Luo 1 , Shenlin Huang 1
Affiliation  

A sulfoxide reduction/C–S bond metathesis cascade between sulfoxides and alkyl bromides has been developed to access high-value sulfides without the use of any catalysts or bases. In this cascade, classical Kornblum oxidation is employed to reduce sulfoxides with alkyl bromides in ionic liquid. This protocol features high functional tolerance, mild conditions, promising scalability, and sustainable solvents.

中文翻译:

离子液体中的亚砜还原/ C(sp3)-S复分解级联。

已开发出亚砜与烷基溴之间的亚砜还原/ CS键复分解级联反应,可在不使用任何催化剂或碱的情况下获得高价值的硫化物。在该级联反应中,采用经典的Kornblum氧化法在离子液体中用烷基溴还原亚砜。该协议具有高功能耐受性,温和条件,可扩展性和可持续溶剂的特点。
更新日期:2020-07-17
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