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Oxadiazole-Functionalized Fibers for Selective Adsorption of Hg2+
Industrial & Engineering Chemistry Research ( IF 4.2 ) Pub Date : 2020-07-01 , DOI: 10.1021/acs.iecr.0c01562
Huimin Du 1 , Yujia Xie 1 , Haonan Zhang 1 , Anyaegbu Chima 1 , Minli Tao 1, 2 , Wenqin Zhang 1, 3
Affiliation  

Six kinds of 1,3,4-oxadiazole-functionalized fibers were prepared to evaluate the adsorption capacity for Hg2+. Finally, a functionalized fiber (PANp-PMODF) with the best adsorption performance was selected for further research. The PANp-PMODF fiber was characterized by infrared (IR), elemental analysis (EA), scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The PANp-PMODF shows excellent selectivity for mercury ions in a mixed heavy metal ion solution (Hg2+, Ni2+, Pb2+, Zn2+, Ag+, Co2+, Cr3+, Cu2+, and Cd2+), and it can reduce the concentration of Hg2+ to 44 ppb in the actual sewage, which is of great practical value for the treatment of mercury pollution. Furthermore, the adsorbed Hg2+ can be desorbed completely by dilute HNO3 and the PANp-PMODF can be reused many times with excellent recyclability.

中文翻译:

乙二唑功能化纤维对Hg 2+的选择性吸附

制备了六种1,3,4-恶二唑官能化纤维,以评价其对Hg 2+的吸附能力。最后,选择具有最佳吸附性能的功能化纤维(PAN p-PMOD F)进行进一步研究。PAN p-PMOD F纤维的特征在于红外(IR),元素分析(EA),扫描电子显微镜(SEM),X射线衍射(XRD)和X射线光电子能谱(XPS)。PAN p-PMOD F对混合重金属离子溶液(Hg 2 +,Ni 2 +,Pb 2 +,Zn 2 +,Ag +,Co 2 +,Cr 3+,Cu2+和Cd 2+),可将实际污水中的Hg 2+浓度降低至44 ppb,对于处理汞污染具有很大的实用价值。此外,被吸附的Hg 2+可以被稀的HNO 3完全解吸,并且PAN p-PMOD F可以以优异的循环利用性多次重复使用。
更新日期:2020-07-22
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