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A Total Synthesis of (±)‐Ceratopicanol via Palladium Catalyzed Reductive Cyclization
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-06-30 , DOI: 10.1002/ejoc.202000769
Rira Kim 1 , Sanghyeon Lee 1 , Jaeyeon Lee 1 , Hee-Yoon Lee 1
Affiliation  

An efficient total synthesis of ceratopicanol was achieved through successive Pd catalyzed reductive cycloaddition and cyclization reactions. The Pd mediated cyclization reaction to form a triquinane structure demonstrated that a small structural difference changed the reaction pathway either to form different structures or reduced non‐cyclized product depending on the reaction conditions.
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中文翻译:

钯催化还原环化法合成(±)-陶瓷胺醇

通过连续的Pd催化的还原性环加成反应和环化反应,实现了高效的全氟辛烷醇合成。由Pd介导的环化反应形成三structure烷结构表明,微小的结构差异会根据反应条件改变反应路径以形成不同的结构或还原未环化的产物。
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更新日期:2020-08-17
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