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Strongly Anchoring Polysulfides by Hierarchical Fe 3 O 4 /C 3 N 4 Nanostructures for Advanced Lithium–Sulfur Batteries
Nano-Micro Letters ( IF 26.6 ) Pub Date : 2020-07-01 , DOI: 10.1007/s40820-020-00475-5
Soochan Kim 1 , Simindokht Shirvani-Arani 2 , Sungsik Choi 1 , Misuk Cho 1 , Youngkwan Lee 1
Affiliation  

  • A multi-functional interlayer for Li–S batteries has been developed to efficiently regulate the shuttle effect and enhance the sulfur utilization using hierarchical Fe3O4/C3N4 nanostructures.

  • C3N4 nanotube exhibits high surface area and high affinity toward LPS, and the decorating Fe3O4 nanospheres on the surface of C3N4 nanotube accelerate the adsorption of LPS and improve the electronic pathways.

  • The combination of Fe3O4 nanospheres and C3N4 nanotube leads to remarkable battery performance with 400% improvements in specific capacity compared with Li–S battery without using interlayer and a low capacity decay per cycle of 0.02% at 2 C over 1000 cycles.



中文翻译:

Fe 3 O 4 / C 3 N 4层级结构为高级锂硫电池牢固锚固的多硫化物

  • 已经开发出用于Li–S电池的多功能中间层,以使用分层的Fe 3 O 4 / C 3 N 4纳米结构来有效调节穿梭效应并提高硫的利用率。

  • Ç 3 Ñ 4碳纳米管表现出高的表面面积和朝向LPS高亲和力,并且装饰的Fe 3 ö 4层C的表面上的纳米球3 Ñ 4纳米管加速LPS的吸附和提高电子通路。

  • 与不使用中间层的Li–S电池相比,Fe 3 O 4纳米球和C 3 N 4纳米管的组合可提供卓越的电池性能,比容量提高400%,并且在1000℃2 C下每循环的容量衰减低至0.02%周期。

更新日期:2020-07-01
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