Abstract

The work describes an efficient one-step solvent-free synthesis of ethyltrimethoxysilane through hydrosilylation reaction catalyzed by RuCl₃ ⋅ 3H₂O–H₂O. The procedure involves time point and dose of adding additive water. Excellent yields, short reaction times, and easy reaction handling under solvent-free and mild conditions are the most important advantages of the present protocol. A possible reaction mechanism was discussed by empirical method.

中文翻译：

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乙烯的选择性催化氢化硅烷化。H 2 O促进的RuCl 3⋅3H 2 O催化剂制备乙基三甲氧基硅烷

摘要

工作描述了乙基三甲氧基硅烷的有效的一步无溶剂合成通过的RuCl催化氢化硅烷化反应₃ ⋅3H ₂ O - H ₂ O.该过程涉及时间点，加入添加剂的水剂量。本方案最重要的优点是，优异的收率，较短的反应时间以及在无溶剂和温和条件下易于处理的反应。通过经验方法探讨了可能的反应机理。