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Catalytic Performance and Characterization of Ce-Modified Fe Catalysts Supported on Al 2 O 3 for SCR-C 3 H 8
Catalysis Surveys from Asia ( IF 3 ) Pub Date : 2020-06-30 , DOI: 10.1007/s10563-020-09306-4
Fengguo Tian , Kangkai Li , Yaxin Su

In order to further improve the resistance of the catalysts to H2O and SO2 during the selective catalytic reduction of NO with C3H8 (SCR-C3H8), Ce was used to modify the Fe-based catalysts. Sol–gel and impregnation methods were adopted to prepare the monolithic cordierite Ce–Fe/Al2O3 catalysts and the SCR-C3H8 testes were carried out in a flow reactor, electrically heated up to 600 °C, and with simulated a flue gas rate of 1.5 L/min. The physical chemical properties of the catalysts were characterized by XRD, N2 adsorption–desorption, SEM, H2-TPR and FT-IR spectra of adsorbed pyridine, etc. Results show that the introduction of Cerium notably enhances the resistance of the Fe/Al2O3/Cordierite catalysts to SO2. 3.5Ce–Fe/Al2O3/Cordierite has the highest C3H8-SCR activity, e.g., the NO reductions are 96.5% and 93% at 600 °C when there was no and 0.02% SO2 in the flue gas, respectively. While the NO reduction by Fe/Al2O3/Cordierite decreased from 88 to 80% in the presence of 0.02% SO2. The addition of Cerium to iron oxide leads to an increase in the Lewis acid sites and the redox property of the catalysts. However, an overload of cerium will reduce the crystallinity of iron oxide nanorods and inhibit the formation of the NO2/NO3 species in the C3H8-SCR reaction, resulting in a decrease in the NO reduction.



中文翻译:

Al 2 O 3负载Ce改性Fe催化剂对SCR-C 3 H 8的催化性能和表征。

为了进一步提高用C 3 H 8(SCR-C 3 H 8)选择性催化还原NO的过程中催化剂对H 2 O和SO 2的耐受性,使用Ce对Fe基催化剂进行改性。采用溶胶-凝胶法和浸渍法制备堇青石整体式Ce-Fe / Al 2 O 3催化剂,SCR-C 3 H 8试样在流动反应器中进行,电加热至600°C,并模拟烟气速率为1.5 L / min。通过XRD,N 2吸附-解吸,SEM,H 2表征了催化剂的物理化学性质。吸附吡啶的-TPR和FT-IR光谱等。结果表明,铈的引入显着增强了Fe / Al 2 O 3 /堇青石催化剂对SO 2的耐受性。3.5Ce–Fe / Al 2 O 3 /堇青石具有最高的C 3 H 8 -SCR活性,例如,在烟气中不存在SO 2和0.02%SO 2的情况下,在600°C下NO的还原率分别为96.5%和93%。, 分别。在0.02%SO 2的存在下,Fe / Al 2 O 3 /堇青石的NO还原率从88%降低至80%。将铈添加到氧化铁中导致路易斯酸位点的增加和催化剂的氧化还原性质。但是,铈的过载会降低的氧化铁纳米棒的结晶性和抑制NO的形成2 / NO 3 -在C物种3 ħ 8 -SCR反应,导致在还原NO的降低。

更新日期:2020-06-30
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