In this paper, one 3D imidazole cyclophane trivalent cation was chosen with the aim of studying conformational behavior. One novel organic-inorganic hybrid supramolecule {L1·(NH4) [Mo8O26]·(H2O)} (1), has been synthesized through the self-assembly reaction. Compound 1 has been expressly confirmed by PXRD, IR, X-ray single crystal diffraction, and TG. Crystallographic analysis shows that the anion of compound 1 is Multi-core structure. TG shows that the stability of compound 1 is relatively good.

中文翻译：

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偶氮连接环烷的杂化超分子：合成，结构和热稳定性

在本文中，为了研究构象行为，选择了一个3D咪唑环烷三价阳离子。通过自组装反应合成了一种新型的有机-无机杂化超分子{L1·（NH4）[Mo8O26]·（H2O）}（1）。通过PXRD，IR，X射线单晶衍射和TG明确证实了化合物1。晶体学分析表明化合物1的阴离子为多核结构。TG表明化合物1的稳定性相对较好。