The self‐assembly of a diamondoid woven supramolecular metal–organic framework wSMOF‐1 has been achieved from intertwined [Ru(tpy)₂]²⁺ (tpy=2,2′,6′,2′′‐terpyridine) complex M1 and cucurbit[8]uril (CB[8]) in water, where the intermolecular dimers formed by the appended aromatic arms of M1 are encapsulated in CB[8]. wSMOF‐1 exhibits ordered pore periodicity in both water and the solid state, as confirmed by a combination of ¹H NMR spectroscopy, UV‐vis absorption, isothermal titration calorimetry, dynamic light scattering, small angle X‐ray scattering and selected area electron diffraction experiments. The woven framework has a pore aperture of 2.1 nm, which allows for the free access of both secondary and primary alcohols and tert‐butyl hydroperoxide (TBHP). Compared with the control molecule [Ru(tpy)₂]Cl₂, the [Ru(tpy)₂]²⁺ unit of wSMOF‐1 exhibits a remarkably higher heterogeneous catalysis activity for the oxidation of alcohols by TBHP in n‐hexane. For the oxidation of 1‐phenylethan‐1‐ol, the yield of acetophenone was increased from 10 % to 95 %.

中文翻译：

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编织的双分子金属有机骨架，包含钌双（三联吡啶）配合物和葫芦[8] uril：增强的醇氧化催化活性。

交织的[Ru（tpy）₂ ] ²⁺（tpy = 2,2'，6'，2''-terpyridine）络合物M1和WSMOF-1构成了类金刚石编织的超分子金属有机框架wSMOF-1的自组装。水中的葫芦[8]尿素（CB [8]），其中由M1的附加芳香族臂形成的分子间二聚体被封装在CB [8]中。wSMOF-1在水和固态中均表现出有序的孔隙周期性，这由以下¹的组合所证实H NMR光谱，紫外可见吸收，等温滴定量热法，动态光散射，小角X射线散射和选定区域电子衍射实验。机织骨架的孔径为2.1 nm，可自由接触仲，伯醇和叔丁基氢过氧化物（TBHP）。与对照相比，分子的[Ru（TPY）₂ ]氯₂，所述的[Ru（TPY）₂ ] ²⁺的单元wSMOF-1表现出对醇的氧化通过TBHP显着更高的非均相催化活性Ñ正己烷。对于1-苯基乙-1-醇的氧化，苯乙酮的产率从10％增加到95％。