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Boron difluoride functionalized (tetrahydroimidazo[1,5-a]pyridin-3-yl)phenols: Highly fluorescent blue emissive materials
Dyes and Pigments ( IF 4.5 ) Pub Date : 2020-06-27 , DOI: 10.1016/j.dyepig.2020.108636
Gioele Colombo , Antonio Romeo , G. Attilio Ardizzoia , Julien Furrer , Bruno Therrien , Stefano Brenna

Some (tetrahydroimidazo[1,5-a]pyridin-3-yl)phenols were reacted with boron trifluoride diethyl etherate and the resulting BF2-functionalized compounds were fully characterized both in solution using 1H, 13C, 11B, 19F NMR spectroscopy and in the solid state (infrared, fluorescence, X-ray). When excited with UV light these boron difluoride derivatives show in dichloromethane solution an intense fluorescence emission in the UV region, with λmax of emission varying from 357 to 390 nm. Good absolute quantum yields are recorded for most of the compounds. In the solid state, they are characterized by a strong blue emission (388–435 nm), with high absolute quantum yields (up to 0.68) and x,y color coordinates (CIE 1931) close to those expected for standard blue. Time-Dependent Density Functional Theory (TD-DFT) calculations were used to define the nature of the electronic transitions and excited states involved in the fluorescence process.



中文翻译:

二氟化硼官能化的(四氢咪唑并[1,5- a ]吡啶-3-基)酚:高荧光蓝色发光材料

使一些(四氢咪唑并[1,5 - a ]吡啶-3-基)酚与三氟化硼二乙基醚化物反应,并使用1 H,13 C,11 B,19 F在溶液中充分表征所得的BF 2官能化化合物NMR光谱和固态(红外,荧光,X射线)。当使用UV激发光,这些二氟化硼衍生物显示在二氯甲烷溶液中在UV区域的强烈的荧光发射,与λ最大发射波长在357至390 nm之间变化。对于大多数化合物,均记录了良好的绝对量子产率。在固态状态下,它们的特点是发出强烈的蓝光(388–435 nm),具有很高的绝对量子产率(最高达0.68)和xy色坐标(CIE 1931),接近于标准蓝色。随时间变化的密度泛函理论(TD-DFT)计算用于定义荧光过程中涉及的电子跃迁和激发态的性质。

更新日期:2020-07-08
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