Intriguing reactivities were encountered en route to the first total synthesis of aromatic C ring vouacapanes featuring a substituted B ring (III and IV ) through exploitation of the pivotal intermediate II . A new modification of the Caglioti reaction had to be developed to allow efficient reductive deoxygenation at low temperature.

中文翻译：

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对映选择性合成的s烷型呋喃二萜：Sucutiniranes C和D的全合成

通过关键中间体II的开发，在首次以取代的B环（III和IV）为特征的芳香族C环vouacapanes的首次总合成中遇到了有趣的反应性。必须开发一种对Caglioti反应的新修饰，以允许在低温下进行有效的还原性脱氧。