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Platinum (II)-doped graphitic carbon nitride with enhanced peroxidase-like activity for detection of glucose and H2O2.
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy ( IF 4.4 ) Pub Date : 2020-06-26 , DOI: 10.1016/j.saa.2020.118649
Guo Zeng 1 , Minghui Duan 2 , Yifan Xu 3 , Fahuan Ge 4 , Weiguo Wang 5
Affiliation  

A platinum (II)-doped graphitic carbon nitride (Pt2+@g-C3N4) nanozyme was prepared in this work. Compared to g-C3N4, Pt2+@g-C3N4 shows enhanced peroxidase-like activity. According to DFT calculations and ESR measurements, the Pt on the surface of g-C3N4 accelerates the decomposition of H2O2 into OH and consequently accelerates TMB oxidation. Furthermore, as a proof of concept, the obtained Pt2+2.30@g-C3N4 was applied in the detection of glucose with an LOD of 0.01 mM. The reproducibility and precision tests of the glucose detection method based on Pt2+2.30@g-C3N4 show that this method is reliable and feasible for the detection of glucose.



中文翻译:

铂(II)掺杂的石墨氮化碳具有增强的过氧化物酶样活性,可检测葡萄糖和H2O2。

在这项工作中,制备了掺杂铂(II)的石墨氮化碳(Pt 2+ @gC 3 N 4)纳米酶。与gC 3 N 4相比,Pt 2+ @gC 3 N 4显示出增强的过氧化物酶样活性。根据DFT计算和ESR测量,gC 3 N 4表面的Pt加速了H 2 O 2分解为OH,因此加速了TMB氧化。此外,作为概念证明,得到的Pt 2+ 2.30 @gC 3 N 4将其用于检测LOD为0.01 mM的葡萄糖。基于Pt 2+ 2.30 @gC 3 N 4的葡萄糖检测方法的重现性和精密度试验表明,该方法对葡萄糖的检测是可靠可行的。

更新日期:2020-07-03
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