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Micelle-Catalyzed Synthesis of Arylmethylidene Derivatives of Malononitrile Trimer and Study of Their Optical Properties
Russian Journal of Organic Chemistry ( IF 0.8 ) Pub Date : 2020-06-26 , DOI: 10.1134/s1070428020050061 A. U. Alekseeva , N. P. Dianov , N. N. Yashchenko , S. V. Zhitar’ , I. N. Bardasov
中文翻译:
胶束催化丙二腈三聚体芳基亚甲基衍生物的合成及其光学性质的研究
更新日期:2020-06-26
Russian Journal of Organic Chemistry ( IF 0.8 ) Pub Date : 2020-06-26 , DOI: 10.1134/s1070428020050061 A. U. Alekseeva , N. P. Dianov , N. N. Yashchenko , S. V. Zhitar’ , I. N. Bardasov
Abstract
Potassium salts of arylmethylidene derivatives of malononitrile trimer were obtained by the reactions of aromatic aldehydes with malononitrile trimer in an aqueous medium under micellar catalysis. The optical properties of the synthesized salts were studied to show they absorb in the range of 313–436 nm, depending on the substituent. Exchange reactions with various metal salts showed that the synthesized derivatives of malononitrile trimer form difficultly soluble compounds with silver salts.中文翻译:
胶束催化丙二腈三聚体芳基亚甲基衍生物的合成及其光学性质的研究