Abstract A mini-review describes the development of the catalysis by Cu(I) complexes aimed at the formation of C–N bond at the Lomonosov MSU during 2010s. The main approach employs the amination of aryl and heteroaryl halides with the amines and polyamines, in this direction a great versatility of starting compounds was achieved: adamantane-containing amines, linear diamines, oxadiamines and polyamines, various aryl iodides and bromides, derivatives of pyridine, and quinoline were used for this purpose. In more peculiar cases, the copper catalysis was used for steroids transformations, including vinylation of azoles, wide-spread “click” reactions for the conjugate syntheses, and successful heterogenezation of the copper catalysts were also undertaken.

中文翻译：

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铜催化C-N键形成的最新成果

摘要 一篇小型综述描述了 2010 年代旨在在罗蒙诺索夫 MSU 形成 C-N 键的 Cu(I) 配合物催化的发展。主要方法采用芳基和杂芳基卤化物与胺和多胺的胺化，在这个方向上实现了起始化合物的广泛用途：含金刚烷胺、线性二胺、氧二胺和多胺、各种芳基碘化物和溴化物、吡啶衍生物和喹啉用于此目的。在更特殊的情况下，铜催化用于类固醇转化，包括唑类的乙烯基化、共轭合成的广泛“点击”反应，以及铜催化剂的成功异质化。