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Rhodium(I) Complexes as Useful Tools for the Activation of Fluoroolefins
Synlett ( IF 2 ) Pub Date : 2020-06-24 , DOI: 10.1055/s-0040-1707156
Thomas Braun 1 , María Talavera
Affiliation  

In this account we describe studies on the reactivity of rhodium(I) complexes of the type [Rh(E)(PEt3)3], where E represents hydrido, fluorido, germyl, boryl or silyl ligands, towards fluorinated olefins. The results are compared with those reported by other research groups on fluoroolefins, as well as with the chemistry of compounds [Rh(E)(PEt3)3] towards fluoroaromatics in terms of selectivity and mechanisms. 1 Introduction 2 Reactivity Towards Fluoroolefins 2.1 Reactivity of Hexafluoropropene 2.2 Reactivity of (E)-1,2,3,3,3-Pentafluoropropene 2.3 Reactivity of 2,3,3,3-Tetrafluoropropene and (E)-1,3,3,3-Tetrafluoropropene 2.4 Reactivity of 3,3,3-Trifluoropropene 2.5 Reactivity of Pentafluorostyrene 3 Conclusion and Perspective

中文翻译:

铑 (I) 配合物作为活化氟烯烃的有用工具

在这个帐户中,我们描述了 [Rh(E)(PEt3)3] 型铑 (I) 配合物对氟化烯烃的反应性研究,其中 E 代表氢化、氟化、锗基、硼基或甲硅烷基配体。在选择性和机理方面,将结果与其他氟烯烃研究小组以及化合物 [Rh(E)(PEt3)3] 对氟芳烃的化学反应进行了比较。1 介绍 2 对氟烯烃的反应性 2.1 六氟丙烯的反应性 2.2 (E)-1,2,3,3,3-五氟丙烯的反应性 2.3 2,3,3,3-四氟丙烯和 (E)-1,3,3 的反应性,3-四氟丙烯 2.4 3,3,3-三氟丙烯的反应性 2.5 五氟苯乙烯的反应性 3 结论与展望
更新日期:2020-06-24
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